About: Photorelease of triplet and singlet oxygen from dioxygen complexes

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Photolysis of some dioxygen transition metal complexes leads to the release of oxygen molecules in two electronic states, namely, in the ground triplet state 3Σg and the lowest excited singlet state 1Δg. The reaction involves electron transfer from the dioxygen moiety to the central metal ion. In the reported cases, the photoreaction of peroxo complexes is activated by ligand-to-metal charge transfer excitation. The mechanism of singlet oxygen photorelease relates to intramolecular energy transfer and differs in principle from the photosensitization process. Consequently, the photorelease can be viewed as a new route to dioxygen activation by spin inversion of the ground state oxygen to singlet oxygen. Photolysis of some dioxygen transition metal complexes leads to the release of oxygen molecules in two electronic states, namely, in the ground triplet state 3Σg and the lowest excited singlet state 1Δg. The reaction involves electron transfer from the dioxygen moiety to the central metal ion. In the reported cases, the photoreaction of peroxo complexes is activated by ligand-to-metal charge transfer excitation. The mechanism of singlet oxygen photorelease relates to intramolecular energy transfer and differs in principle from the photosensitization process. Consequently, the photorelease can be viewed as a new route to dioxygen activation by spin inversion of the ground state oxygen to singlet oxygen. (en)
Title	Photorelease of triplet and singlet oxygen from dioxygen complexes Photorelease of triplet and singlet oxygen from dioxygen complexes (en)
skos:prefLabel	Photorelease of triplet and singlet oxygen from dioxygen complexes Photorelease of triplet and singlet oxygen from dioxygen complexes (en)
skos:notation	RIV/61388980:_____/11:00367782!RIV12-AV0-61388980
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GAP207/10/1447), P(GAP208/10/1678), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	23-24
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Lang, Kamil Wagnerová, Dana Marie
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	220288
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/11:00367782
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	singlet oxygen; triplet oxygen; photochemical elimination; photorelease; Dioxygen complex (en)
http://linked.open.../riv/klicoveSlovo	singlet oxygen Dioxygen complex photochemical elimination photorelease triplet oxygen
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[3DF9DCFEE46F]
http://linked.open...i/riv/nazevZdroje	Coordination Chemistry Reviews
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Photophysics and Photochemistry of Self-Assembled Nanostructures Photoactive hybrid materials
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	255
http://linked.open...iv/tvurceVysledku	Lang, Kamil Wagnerová, Dana Marie
http://linked.open...ain/vavai/riv/wos	000297530000010
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	0010-8545
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.ccr.2011.06.017

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