About: Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes

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About: Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A ruthenium complex (Hoveyda–Grubbs second-generation) catalyzed cross-metathesis of allylcarboranes with perfluoroalkylpropenes under standard reaction conditions furnished perfluoroalkylated carboranes in good isolated yields (31–53%). The reaction proceeded with various carboranes and carborane sandwich complexes bearing the bridging allylthioether moiety. This method constitutes a simple and versatile procedure for the preparation of fluorophilic carboranes. A ruthenium complex (Hoveyda–Grubbs second-generation) catalyzed cross-metathesis of allylcarboranes with perfluoroalkylpropenes under standard reaction conditions furnished perfluoroalkylated carboranes in good isolated yields (31–53%). The reaction proceeded with various carboranes and carborane sandwich complexes bearing the bridging allylthioether moiety. This method constitutes a simple and versatile procedure for the preparation of fluorophilic carboranes. (en)
Title	Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes (en)
skos:prefLabel	Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes (en)
skos:notation	RIV/61388980:_____/10:00355604!RIV11-MSM-61388980
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(LC06070), P(LC06077), P(LC523), S, Z(AV0Z40320502), Z(AV0Z40550506), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	6
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Janoušek, Zbyněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	291544
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/10:00355604
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	metathesis; perfluoroalkylation; ruthenium; carboranes; metallacarboranes (en)
http://linked.open.../riv/klicoveSlovo	carboranes metallacarboranes metathesis ruthenium perfluoroalkylation
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[EE02836D1CC5]
http://linked.open...i/riv/nazevZdroje	Synlett
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Center of Chemical Genetics The structure and synthetic applications of transition metal complexes
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	-
http://linked.open...iv/tvurceVysledku	Dračínský, Martin Janoušek, Zbyněk Eignerová, Barbara Kotora, M.
http://linked.open...ain/vavai/riv/wos	000275848800008
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0936-5214
number of pages	4 (xsd:int)

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