About: Cyclopentadienyl ruthenium comlexes with tricarbolide ligands     Goto   Sponge   NotDistinct   Permalink

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  • Reaction of the tricarbollide anion [7,8,9-C3B8H11](-) (1a) with the naphthalene complex [CpRu(C10H8)](+) under visible light irradiation in CH2Cl2 gives the 12-vertex closo-rthenacarborane 1-Cp-1,2,3,5-RuC3B8H11 (2; 87% yield). This complex was also obtained by reaction of 1a with CpRu(cod) Cl (97%). Upon heating at 80 C in toluene 2 rearranges into isomer 1-Cp-1,2,4,10-RuC3B8H11 (3; 63%). Irradiation of 1a with [CpRu(C10H8)](+) in acetone gives the 11-vertex closo-1-Cp-1,2,3,4-RuC3B7H10 (4; 32%). The latter was also prepared by reaction of 1a with [CpRu(MeCN)(3)]+ (59%). Compound 2 slowly undergoes cage contraction in acetone giving 4.
  • Reaction of the tricarbollide anion [7,8,9-C3B8H11](-) (1a) with the naphthalene complex [CpRu(C10H8)](+) under visible light irradiation in CH2Cl2 gives the 12-vertex closo-rthenacarborane 1-Cp-1,2,3,5-RuC3B8H11 (2; 87% yield). This complex was also obtained by reaction of 1a with CpRu(cod) Cl (97%). Upon heating at 80 C in toluene 2 rearranges into isomer 1-Cp-1,2,4,10-RuC3B8H11 (3; 63%). Irradiation of 1a with [CpRu(C10H8)](+) in acetone gives the 11-vertex closo-1-Cp-1,2,3,4-RuC3B7H10 (4; 32%). The latter was also prepared by reaction of 1a with [CpRu(MeCN)(3)]+ (59%). Compound 2 slowly undergoes cage contraction in acetone giving 4. (en)
Title
  • Cyclopentadienyl ruthenium comlexes with tricarbolide ligands
  • Cyclopentadienyl ruthenium comlexes with tricarbolide ligands (en)
skos:prefLabel
  • Cyclopentadienyl ruthenium comlexes with tricarbolide ligands
  • Cyclopentadienyl ruthenium comlexes with tricarbolide ligands (en)
skos:notation
  • RIV/61388980:_____/10:00354532!RIV11-MSM-61388980
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(LC523), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika
  • 11
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 252607
http://linked.open...ai/riv/idVysledku
  • RIV/61388980:_____/10:00354532
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • boron; metallacarborane; ruthenium; tricarbollide (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [4DB054A24A4E]
http://linked.open...i/riv/nazevZdroje
  • Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 75
http://linked.open...iv/tvurceVysledku
  • Holub, Josef
  • Kudinov, A. R.
  • Glukhov, I. V.
  • Perekalin, D. S.
  • Trifonova, E. A.
http://linked.open...ain/vavai/riv/wos
  • 000284230500006
http://linked.open...n/vavai/riv/zamer
issn
  • 0010-0765
number of pages
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