About: Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces

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About: Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The interaction between flat silver surfaces and carboranethiol derivatives, and its relevance regarding the molecular protection of silver against corrosion by hydrogen sulphide, are reported here. A comparison of the protective qualities of four carboranethiols (1-HS-1,2-C2B10H11, 1,2-(HS)(2)-1,2-C2B10H10, 9,12-(HS)(2)-1,2-C2B10H10, and 1,12-(HS)(2)-1,2-C2B10H10) with several organic thiols (1-butanethiol, 1-octanethiol, 1-dodecanethiol, benzene-1,2-dithiol, benzenethiol, and sodium 2-mercaptoethanesulphonate) is provided. All these derivatives are categorized according to their capacity to inhibit the interaction of silver with H2S in the presence of water molecules in the gas phase. We found that significantly better molecular protection for silver surfaces is afforded by the carboranethiol derivatives, and, of these, 9,12-(HS)(2)-1,2-C2B10H10 proved to be particularly effective. The interaction between flat silver surfaces and carboranethiol derivatives, and its relevance regarding the molecular protection of silver against corrosion by hydrogen sulphide, are reported here. A comparison of the protective qualities of four carboranethiols (1-HS-1,2-C2B10H11, 1,2-(HS)(2)-1,2-C2B10H10, 9,12-(HS)(2)-1,2-C2B10H10, and 1,12-(HS)(2)-1,2-C2B10H10) with several organic thiols (1-butanethiol, 1-octanethiol, 1-dodecanethiol, benzene-1,2-dithiol, benzenethiol, and sodium 2-mercaptoethanesulphonate) is provided. All these derivatives are categorized according to their capacity to inhibit the interaction of silver with H2S in the presence of water molecules in the gas phase. We found that significantly better molecular protection for silver surfaces is afforded by the carboranethiol derivatives, and, of these, 9,12-(HS)(2)-1,2-C2B10H10 proved to be particularly effective. (en)
Title	Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces (en)
skos:prefLabel	Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces (en)
skos:notation	RIV/61388980:_____/10:00349146!RIV11-MSM-61388980
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IAA400320901), P(KAN100400702), P(KAN400480701), P(LC06041), P(LC523), Z(AV0Z10480505), Z(AV0Z40320502), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	16-17
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Lang, Kamil Plešek, Jaromír Baše, Tomáš Macháček, Jan Bould, Jonathan Londesborough, Michael Geoffrey Stephen
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	249620
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/10:00349146
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	silver; self assembly; corrosion; nanostructure (en)
http://linked.open.../riv/klicoveSlovo	corrosion silver self assembly nanostructure
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[0D6612897119]
http://linked.open...i/riv/nazevZdroje	Surface and Coatings Technology
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	6 (xsd:int)
http://linked.open...cetTvurcuVysledku	8 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Gold and silver surfaces modified with functional derivatives of boron hydrides Nanostructured materials for catalytic, electrocatalytic and sorption applications NANOSTRUCTURES BASED ON CARBON AND POLYMERS FOR APPLICATION IN BIOELECTRONIC AND MEDICINE Preparation, modification and characterization of materials by energetic radiation.
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	204
http://linked.open...iv/tvurceVysledku	Bould, Jonathan Havránek, Vladimír Lang, Kamil Londesborough, Michael Geoffrey Stephen Macháček, Jan Plešek, Jaromír Bastl, Zdeněk Baše, Tomáš
http://linked.open...ain/vavai/riv/wos	000277736100018
http://linked.open...n/vavai/riv/zamer	Jaderná fyzika a příbuzné obory v základním, aplikovaném a interdisciplinárním výzkumu Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0257-8972
number of pages	8 (xsd:int)

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