About: Porphyrins intercalated in Zn/Al and Mg/Al layered double hydroxides: properties and structural arrangement

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The arrangement of porphyrin molecules in the interlayer space of layered double hydroxides (LDH) has been studied by a combination of experimental techniques and molecular dynamics simulations. Intercalation of 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrins (TPPS) into ZnRAl and MgRAl LDH hosts led to a gallery height of about 15.5 angstrom that is comparable with the size of the porphyrin molecules. The porphyrin sulfonate groups arc located at about 4 angstrom from the center of the hydroxide layers that is consistent with hydrogen bonding interactions between the sulfonate groups and OH groups of the layers. The aromatic ring system in the middle of the gallery is rather disordered A large number of in-plane diffraction lines suggests that the rigidity of the porphyrin framework has a beneficial effect on the layer ordering. The arrangement of porphyrin molecules in the interlayer space of layered double hydroxides (LDH) has been studied by a combination of experimental techniques and molecular dynamics simulations. Intercalation of 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrins (TPPS) into ZnRAl and MgRAl LDH hosts led to a gallery height of about 15.5 angstrom that is comparable with the size of the porphyrin molecules. The porphyrin sulfonate groups arc located at about 4 angstrom from the center of the hydroxide layers that is consistent with hydrogen bonding interactions between the sulfonate groups and OH groups of the layers. The aromatic ring system in the middle of the gallery is rather disordered A large number of in-plane diffraction lines suggests that the rigidity of the porphyrin framework has a beneficial effect on the layer ordering. (en)
Title	Porphyrins intercalated in Zn/Al and Mg/Al layered double hydroxides: properties and structural arrangement Porphyrins intercalated in Zn/Al and Mg/Al layered double hydroxides: properties and structural arrangement (en)
skos:prefLabel	Porphyrins intercalated in Zn/Al and Mg/Al layered double hydroxides: properties and structural arrangement Porphyrins intercalated in Zn/Al and Mg/Al layered double hydroxides: properties and structural arrangement (en)
skos:notation	RIV/61388980:_____/10:00346803!RIV11-GA0-61388980
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/07/1424), P(GAP207/10/1447), Z(AV0Z40320502), Z(AV0Z40400503), Z(MSM0021620835), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	8
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Kafuňková, Eva Klementová, Mariana Lang, Kamil Mosinger, Jiří Bezdička, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	280043
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/10:00346803
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	hydrotalcite-like compounds; molecular-dynamic simulations; photophysical properties (en)
http://linked.open.../riv/klicoveSlovo	photophysical properties hydrotalcite-like compounds molecular-dynamic simulations
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[C4DA0B4D419B]
http://linked.open...i/riv/nazevZdroje	Chemistry of Materials
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	5 (xsd:int)
http://linked.open...cetTvurcuVysledku	9 (xsd:int)
http://linked.open...vavai/riv/projekt	Photoactive hybrid materials Self-assembled porphyrin nanostructures
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	22
http://linked.open...iv/tvurceVysledku	Bezdička, Petr Klementová, Mariana Kubát, Pavel Lang, Kamil Mosinger, Jiří Pospíšil, M. Kovář, P. Taviot-Guého, Ch. Káfuňková, Eva
http://linked.open...ain/vavai/riv/wos	000276817200011
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace Fyzika molekulárních, makromolekulárních a biologických systémů Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0897-4756
number of pages	10 (xsd:int)

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