About: Systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into carborane cages via [(eta(6)-arene)Fe](2+) dications. A series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] complexes. Reliable synthesis of polymethylated [(eta(6)-arene)(...

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About: Systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into carborane cages via [(eta(6)-arene)Fe](2+) dications. A series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] complexes. Reliable synthesis of polymethylated [(eta(6)-arene)(... Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Developed was a systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into a carborane cage. Reactions between [(eta(6)-arene)(2)Fe](PF6)(2) salts and Tl-2[nido-7,8-C2B9H11] in refluxing (CH2)(2)Cl-2 generated a series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] neutral complexes with variable types of polymethylated arene ligands in the structure. The structures of durene and hexamethylbenzene complexes were established by X-ray diffraction analyses. The work also shows that the original hi temperature method for the preparation of the [(eta(6)-arene)(2)Fe](2+) dications fails for mesitylene and durene compounds, which was overcome by a reliable room-temperature modification. Developed was a systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into a carborane cage. Reactions between [(eta(6)-arene)(2)Fe](PF6)(2) salts and Tl-2[nido-7,8-C2B9H11] in refluxing (CH2)(2)Cl-2 generated a series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] neutral complexes with variable types of polymethylated arene ligands in the structure. The structures of durene and hexamethylbenzene complexes were established by X-ray diffraction analyses. The work also shows that the original hi temperature method for the preparation of the [(eta(6)-arene)(2)Fe](2+) dications fails for mesitylene and durene compounds, which was overcome by a reliable room-temperature modification. (en)
Title	Systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into carborane cages via [(eta(6)-arene)Fe](2+) dications. A series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] complexes. Reliable synthesis of polymethylated [(eta(6)-arene)(... Systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into carborane cages via [(eta(6)-arene)Fe](2+) dications. A series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] complexes. Reliable synthesis of polymethylated [(eta(6)-arene)(... (en)
skos:prefLabel	Systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into carborane cages via [(eta(6)-arene)Fe](2+) dications. A series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] complexes. Reliable synthesis of polymethylated [(eta(6)-arene)(... Systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into carborane cages via [(eta(6)-arene)Fe](2+) dications. A series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] complexes. Reliable synthesis of polymethylated [(eta(6)-arene)(... (en)
skos:notation	RIV/61388980:_____/09:00340428!RIV10-MSM-61388980
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(LC523), Z(AV0Z40320502), Z(MSM0021627501)
http://linked.open...iv/cisloPeriodika	23
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Holub, Josef Štíbr, Bohumil Kvíčalová, Magdalena Bakardjiev, Mario
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	345251
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/09:00340428
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	organotransition-metal matallacarborane; magnetic-resonance spectroscopy; iron complexes (en)
http://linked.open.../riv/klicoveSlovo	magnetic-resonance spectroscopy iron complexes organotransition-metal matallacarborane
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[844F5847B703]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	48
http://linked.open...iv/tvurceVysledku	Bakardjiev, Mario Holub, Josef Kvíčalová, Magdalena Růžička, A. Štíbr, Bohumil
http://linked.open...ain/vavai/riv/wos	000272037500017
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí Aimed preparation of special compounds and materials and investigation of their physical and chemical properties and supramolecular structures
issn	0020-1669
number of pages	3 (xsd:int)

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