About: Reductive degradation of nido-1-CB8H12 into smaller-cage carborane systems via new monocarbaboranes [arachno-5-CB8H13](-) and closo-2-CB6H8     Goto   Sponge   NotDistinct   Permalink

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  • Treatment of the nido-1-CB8H12 (1) carborane with NaBH, in THF at ambient temperature led to the isolation of the stable [arachno-5-CB8H13](-) (2(-)), which was isolated as Na+[5-CB8H13](-).1.5THF and PPh4+[5-CB8H13](-) in almost quantitative yield.The method gave superior results to those carried out using GIAO-HF when relating the calculated B-11 NMR chemical shifts to experimental data.
  • Treatment of the nido-1-CB8H12 (1) carborane with NaBH, in THF at ambient temperature led to the isolation of the stable [arachno-5-CB8H13](-) (2(-)), which was isolated as Na+[5-CB8H13](-).1.5THF and PPh4+[5-CB8H13](-) in almost quantitative yield.The method gave superior results to those carried out using GIAO-HF when relating the calculated B-11 NMR chemical shifts to experimental data. (en)
Title
  • Reductive degradation of nido-1-CB8H12 into smaller-cage carborane systems via new monocarbaboranes [arachno-5-CB8H13](-) and closo-2-CB6H8
  • Reductive degradation of nido-1-CB8H12 into smaller-cage carborane systems via new monocarbaboranes [arachno-5-CB8H13](-) and closo-2-CB6H8 (en)
skos:prefLabel
  • Reductive degradation of nido-1-CB8H12 into smaller-cage carborane systems via new monocarbaboranes [arachno-5-CB8H13](-) and closo-2-CB6H8
  • Reductive degradation of nido-1-CB8H12 into smaller-cage carborane systems via new monocarbaboranes [arachno-5-CB8H13](-) and closo-2-CB6H8 (en)
skos:notation
  • RIV/61388980:_____/08:00341227!RIV10-MSM-61388980
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/05/2646), P(LC523), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika
  • 21
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 391859
http://linked.open...ai/riv/idVysledku
  • RIV/61388980:_____/08:00341227
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • boranes; boron degradation; carboranes (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [0EF7A7C26045]
http://linked.open...i/riv/nazevZdroje
  • Chemistry - A European Journal
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 14
http://linked.open...iv/tvurceVysledku
  • Bakardjiev, Mario
  • Holub, Josef
  • Štíbr, Bohumil
  • Hnyk, Drahomír
http://linked.open...ain/vavai/riv/wos
  • 000258092400026
http://linked.open...n/vavai/riv/zamer
issn
  • 0947-6539
number of pages
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