About: Photochemical arene exchange in the ferracarborane complex [1-(eta-C6H6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+)

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About: Photochemical arene exchange in the ferracarborane complex [1-(eta-C6H6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The benzene complex [1-(eta-C6H6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+) (3a) was synthesized by the photochemical reaction of [(eta(5)-C6H7)Fe(eta-C6H6)](+) (1) with the anion [7-(BuNH)-N-t-7,8,9-C3B8H10](-) followed by the treatment of ferracarborane 1-(eta(5)-C6H7)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10 (2) with hydrochloric acid. The benzene ligand in cation 3a is replaced by alkyl-substituted benzenes under visible light irradiation in CH2Cl2 to form [1-(eta-C6R6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+) (3b-e; C6R6 is toluene (b), mesitylene (c), hexamethylbenzene (d), or anisole (e)). The structure of [3c]PF6 was established by X-ray diffraction. The benzene complex [1-(eta-C6H6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+) (3a) was synthesized by the photochemical reaction of [(eta(5)-C6H7)Fe(eta-C6H6)](+) (1) with the anion [7-(BuNH)-N-t-7,8,9-C3B8H10](-) followed by the treatment of ferracarborane 1-(eta(5)-C6H7)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10 (2) with hydrochloric acid. The benzene ligand in cation 3a is replaced by alkyl-substituted benzenes under visible light irradiation in CH2Cl2 to form [1-(eta-C6R6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+) (3b-e; C6R6 is toluene (b), mesitylene (c), hexamethylbenzene (d), or anisole (e)). The structure of [3c]PF6 was established by X-ray diffraction. (en)
Title	Photochemical arene exchange in the ferracarborane complex [1-(eta-C6H6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+) Photochemical arene exchange in the ferracarborane complex [1-(eta-C6H6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+) (en)
skos:prefLabel	Photochemical arene exchange in the ferracarborane complex [1-(eta-C6H6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+) Photochemical arene exchange in the ferracarborane complex [1-(eta-C6H6)-12-(BuNH)-N-t-1,2,4,12-FeC3B8H10](+) (en)
skos:notation	RIV/61388980:_____/08:00340425!RIV10-AV0-61388980
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	11
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Holub, Josef
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	386526
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/08:00340425
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	arene complexes; iron; metallacarboranes; sendwich compounds (en)
http://linked.open.../riv/klicoveSlovo	iron metallacarboranes arene complexes sendwich compounds
http://linked.open...odStatuVydavatele	RU - Ruská federace
http://linked.open...ontrolniKodProRIV	[0446A3D82AA4]
http://linked.open...i/riv/nazevZdroje	Russian Chemical Bulletin
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	57
http://linked.open...iv/tvurceVysledku	Holub, Josef Kudinov, A. R. Loginov, D. A. Petrovskii, P. V. Starikova, Z. A. Vinogradov, M. M.
http://linked.open...ain/vavai/riv/wos	000271939100011
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	1066-5285
number of pages	4 (xsd:int)

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