About: Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB9} and {PtCB9} metallaheteroboranes

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About: Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB9} and {PtCB9} metallaheteroboranes Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Je popsán vznik jedenáctivrcholových komplexů rhodia a platiny, které v molekule obsahují desetivrcholový azaboranový a karbaboranový klastr jako ligand vázaný na kov. (cs) The metal-to-heteroborane bonding sphere of 1 is fluxional, with a Delta G(double dagger) value of 48.4 kJ mol(-1). DFT calculations on the model compounds [8,8-(PH3)(2)-nido-8,7-RhNB9H11] (1a) and [8,8-(PH3)(2)-nido-8,7-RhSB9H10] (4a) have been carried out to define the fluxional process and the intermediates involved. The metal-to-heteroborane bonding sphere of 1 is fluxional, with a Delta G(double dagger) value of 48.4 kJ mol(-1). DFT calculations on the model compounds [8,8-(PH3)(2)-nido-8,7-RhNB9H11] (1a) and [8,8-(PH3)(2)-nido-8,7-RhSB9H10] (4a) have been carried out to define the fluxional process and the intermediates involved. (en)
Title	Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB9} and {PtCB9} metallaheteroboranes Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB9} and {PtCB9} metallaheteroboranes (en) Polyedrická metalaheteroboranová chemie. Syntéza, spektroskopie, struktura a dynamika jedenáctivrcholových RhNB9 a PtCB9 metala heteroboranů (cs)
skos:prefLabel	Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB9} and {PtCB9} metallaheteroboranes Polyhedral metallaheteroborane chemistry. Synthesis, spectroscopy, structure and dynamics of eleven-vertex {RhNB9} and {PtCB9} metallaheteroboranes (en) Polyedrická metalaheteroboranová chemie. Syntéza, spektroskopie, struktura a dynamika jedenáctivrcholových RhNB9 a PtCB9 metala heteroboranů (cs)
skos:notation	RIV/61388980:_____/07:00097276!RIV08-AV0-61388980
http://linked.open.../vavai/riv/strany	2885;2897
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	27
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Holub, Josef Štíbr, Bohumil
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	442167
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/07:00097276
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	metallaheteroborane chemistry (en)
http://linked.open.../riv/klicoveSlovo	metallaheteroborane chemistry
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[7A77AC8E60D6]
http://linked.open...i/riv/nazevZdroje	Dalton Transactions
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	-
http://linked.open...iv/tvurceVysledku	Holub, Josef Kennedy, J. D. Macias, R. Štíbr, Bohumil Thornton-Pett, M. Bould, J.
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	1477-9226
number of pages	13 (xsd:int)

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