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  • A series of Schiff bases 2[n] with n = 4, 6, 8, 10, 12, and 18 was prepared by the condensation of 9,9'-diaminobis(tricarbollide)Fe(II) (1b) with appropriate 4-alkoxybenzaldehydes (3[n]). Thermal analysis showed that they form nematic and smectic phases with clearing temperatures above 200 C. Comparative studies of series 2[n] and its organic analogs demonstrated that the effectiveness of bis(tricarbollide)Fe(II) in supporting liquid crystalline phases is between that of benzene and biphenyl for n 18 and lower than that of benzene for n = . The photophysical properties were investigated for the butoxy derivative 2[4] and modeled using ZINDO calculations.
  • A series of Schiff bases 2[n] with n = 4, 6, 8, 10, 12, and 18 was prepared by the condensation of 9,9'-diaminobis(tricarbollide)Fe(II) (1b) with appropriate 4-alkoxybenzaldehydes (3[n]). Thermal analysis showed that they form nematic and smectic phases with clearing temperatures above 200 C. Comparative studies of series 2[n] and its organic analogs demonstrated that the effectiveness of bis(tricarbollide)Fe(II) in supporting liquid crystalline phases is between that of benzene and biphenyl for n 18 and lower than that of benzene for n = . The photophysical properties were investigated for the butoxy derivative 2[4] and modeled using ZINDO calculations. (en)
  • Srovnávací studie derivátů ferra bis(trikarbollidu) pro kapalné krystaly. (cs)
Title
  • Liquid Crystalline Derivatives of Bis(tricarbollide)Fe(II)
  • Liquid Crystalline Derivatives of Bis(tricarbollide)Fe(II) (en)
  • Deriváty ferra bis(trikarbollidu) pro kapalné krystaly (cs)
skos:prefLabel
  • Liquid Crystalline Derivatives of Bis(tricarbollide)Fe(II)
  • Liquid Crystalline Derivatives of Bis(tricarbollide)Fe(II) (en)
  • Deriváty ferra bis(trikarbollidu) pro kapalné krystaly (cs)
skos:notation
  • RIV/61388980:_____/07:00096638!RIV08-AV0-61388980
http://linked.open.../vavai/riv/strany
  • 6078;6082
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika
  • 15
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 431181
http://linked.open...ai/riv/idVysledku
  • RIV/61388980:_____/07:00096638
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Bis(tricarbollide)Fe(II) (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [0767A2A52FC1]
http://linked.open...i/riv/nazevZdroje
  • Inorganic Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 46
http://linked.open...iv/tvurceVysledku
  • Grüner, Bohumír
  • Kaszynski, P.
  • Januszko, A.
http://linked.open...n/vavai/riv/zamer
issn
  • 0020-1669
number of pages
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