About: Electrophilic halogenation of nido-5,6-C2B8H12     Goto   Sponge   NotDistinct   Permalink

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Description
  • Elektrofilní halogenace nido-5,6- C2B8H12. (cs)
  • Room-temperature chlorination of the dicarbaborane nido-5,6-C2B8H12 ( 1) with CCl4 in the presence of anhydrous AlCl3 yielded a mixture of 7-Cl-5,6-C2B8H11 (7-Cl-1) ( yield 34 percent), 4-Cl-5,6-C2B8H11 (4- Cl-1) ( yield 20 percent), 3-Cl-5,6-C2B8H11 (3- Cl-1) ( yield 21 percent), and 3,4-Cl-2-5,6- C2B8H10 (3,4- Cl-2- 1) ( yield 26 percent), while a trisubstituted derivative, 3,4,7-Cl-3- 5,6-C2B8H9 (3,4,7-Cl-3- 1) ( yield 80 percent), was isolated as a sole product at reflux.
  • Room-temperature chlorination of the dicarbaborane nido-5,6-C2B8H12 ( 1) with CCl4 in the presence of anhydrous AlCl3 yielded a mixture of 7-Cl-5,6-C2B8H11 (7-Cl-1) ( yield 34 percent), 4-Cl-5,6-C2B8H11 (4- Cl-1) ( yield 20 percent), 3-Cl-5,6-C2B8H11 (3- Cl-1) ( yield 21 percent), and 3,4-Cl-2-5,6- C2B8H10 (3,4- Cl-2- 1) ( yield 26 percent), while a trisubstituted derivative, 3,4,7-Cl-3- 5,6-C2B8H9 (3,4,7-Cl-3- 1) ( yield 80 percent), was isolated as a sole product at reflux. (en)
Title
  • Electrophilic halogenation of nido-5,6-C2B8H12
  • Electrophilic halogenation of nido-5,6-C2B8H12 (en)
  • Elektrofilní halogenace nido-5,6- C2B8H12 (cs)
skos:prefLabel
  • Electrophilic halogenation of nido-5,6-C2B8H12
  • Electrophilic halogenation of nido-5,6-C2B8H12 (en)
  • Elektrofilní halogenace nido-5,6- C2B8H12 (cs)
skos:notation
  • RIV/61388980:_____/06:00050975!RIV07-GA0-61388980
http://linked.open.../vavai/riv/strany
  • 1549;1556
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/05/2646), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika
  • 11-12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 473841
http://linked.open...ai/riv/idVysledku
  • RIV/61388980:_____/06:00050975
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • boranes; dicarbaboranes; electrophilic substitutions (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [63AE78035A01]
http://linked.open...i/riv/nazevZdroje
  • Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 71
http://linked.open...iv/tvurceVysledku
  • Bakardjiev, Mario
  • Holub, Josef
  • Štíbr, Bohumil
http://linked.open...n/vavai/riv/zamer
issn
  • 0010-0765
number of pages
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