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rdf:type
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Description
| - Pentafluoronitrosulfan, SF5NO2. (cs)
- The synthesis of pentafluoronitrosulfane, SF5NO2, is accomplished either by reacting N(SF5)(3) with NO2 or by the photolysis of a SF5Br/NO2 mixture using diazo lamps. The product is purified by treatment with CsF and repeated trap-to-trap condensation. The solid compound melts at -78 degrees C, and the extrapolated boiling point is 9 degrees C. SF5NO2 is characterized by F-19, N-15 NMR, IR, Raman, and UV spectroscopy as well as by mass spectrometry. The molecular structure of SF5NO2 is determined by gas electron diffraction. The experimental geometry and vibrational spectrum are reproduced reasonably well by quantum chemical calculations.
- The synthesis of pentafluoronitrosulfane, SF5NO2, is accomplished either by reacting N(SF5)(3) with NO2 or by the photolysis of a SF5Br/NO2 mixture using diazo lamps. The product is purified by treatment with CsF and repeated trap-to-trap condensation. The solid compound melts at -78 degrees C, and the extrapolated boiling point is 9 degrees C. SF5NO2 is characterized by F-19, N-15 NMR, IR, Raman, and UV spectroscopy as well as by mass spectrometry. The molecular structure of SF5NO2 is determined by gas electron diffraction. The experimental geometry and vibrational spectrum are reproduced reasonably well by quantum chemical calculations. (en)
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Title
| - Pentafluoronitrosulfane, SF5NO2
- Pentafluoronitrosulfan, SF5NO2 (cs)
- Pentafluoronitrosulfane, SF5NO2 (en)
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skos:prefLabel
| - Pentafluoronitrosulfane, SF5NO2
- Pentafluoronitrosulfan, SF5NO2 (cs)
- Pentafluoronitrosulfane, SF5NO2 (en)
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skos:notation
| - RIV/61388980:_____/06:00040387!RIV07-AV0-61388980
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388980:_____/06:00040387
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - electron-diffraction (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Hnyk, Drahomír
- Willner, H.
- Oberhammer, H.
- Lu, N.
- Thrasher, J. S.
- von Ahsen, S.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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