About: An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I]

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About: An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Zajímavá metalakarboranová uzavřená struktura a plášťová reakce zahrnující halogenaci shluku atomu uhlíku. Struktura[1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] (cs) Cage closure, together with the loss of two boron vertices, of [2,5-(eta(5)-C5Me5)(2)-10-Me-mu-2,5-H-)nido-2,5,1-Rh,CB6H8] (1) using an approximately molar equivalent of elemental iodine and excess triethylamine results in the formation of a new species [1,2-(eta 5-C5Me5)2-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] (2), which is characterized by multinuclear NMR spectroscopy, mass spectrometry, and single-crystal X-ray crystallography. The formation Of Compound 2 involves the elimination of a {B2CH3) moiety from I and an iodination of the single carbon vertex. Cage closure, together with the loss of two boron vertices, of [2,5-(eta(5)-C5Me5)(2)-10-Me-mu-2,5-H-)nido-2,5,1-Rh,CB6H8] (1) using an approximately molar equivalent of elemental iodine and excess triethylamine results in the formation of a new species [1,2-(eta 5-C5Me5)2-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] (2), which is characterized by multinuclear NMR spectroscopy, mass spectrometry, and single-crystal X-ray crystallography. The formation Of Compound 2 involves the elimination of a {B2CH3) moiety from I and an iodination of the single carbon vertex. (en)
Title	An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] Zajímavá metalakarboranová uzavřená struktura a plášťová reakce zahrnující halogenaci shluku atomu uhlíku. Struktura[1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] (cs) An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] (en)
skos:prefLabel	An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] Zajímavá metalakarboranová uzavřená struktura a plášťová reakce zahrnující halogenaci shluku atomu uhlíku. Struktura[1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] (cs) An interesting metallacarborane cage closure and dismantling reaction including the facile halogenation of a cluster carbon atom: Structure of [1,2-(eta(5)-C5Me5)(2)-mu-1,2-H-closo-1,2,3-Rh2CB4H4-3-I] (en)
skos:notation	RIV/61388980:_____/05:00029913!RIV06-MSM-61388980
http://linked.open.../vavai/riv/strany	4967;4970
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(LC523)
http://linked.open...iv/cisloPeriodika	21-22
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Londesborough, Michael Geoffrey Stephen
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	511952
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/05:00029913
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	boranes (en)
http://linked.open.../riv/klicoveSlovo	boranes
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[C5637349D8EE]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	690
http://linked.open...iv/tvurceVysledku	Londesborough, Michael Geoffrey Stephen Kennedy, D. J. Carr, M. J.
issn	0022-328X
number of pages	4 (xsd:int)

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