About: Diphosphacarborane analogues of ferrocene: The synthesis of two isomeric twelve-vertex closo-[(eta(5)-C5H5)FeP2CB8H9] complexes

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About: Diphosphacarborane analogues of ferrocene: The synthesis of two isomeric twelve-vertex closo-[(eta(5)-C5H5)FeP2CB8H9] complexes Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The reaction of the Tl+ salt of the [nido-7,8,9-P2CB8H9](-) anion (1) with [CpFe(CO)(2)I](Cp = eta(5)-C5H5) in refluxing mesitylene for 12 h gives mixed-sandwich [1-Cp-closo-1,2,3,4-FeP2CB8H9] ( 2) ( yield 63%). Reaction of the PPh4+ salt of the isomeric [nido-7,8,10-P2CB8H9](-) anion 3(-) with [CpFe(CO)(2)I] in refluxing mesitylene gives [1-Cp-closo-1,2,3,5-FeP2CB8H9] (4) (yield 56%), isomeric with 2. Compound 4 also results (yield 92%) from the sublimation of 2 under argon at ca. 350degreesC. The constitution of all compounds is established by mass spectrometry, IR spectroscopy and multinuclear NMR spectroscopy (H-1, B-11, P-31, and C-13; two-dimensional [B-11-B-11]-COSY, and H-1-{B-11(selective)), further confirmed in the case of 4 by a single-crystal X-ray diffraction analysis. The reaction of the Tl+ salt of the [nido-7,8,9-P2CB8H9](-) anion (1) with [CpFe(CO)(2)I](Cp = eta(5)-C5H5) in refluxing mesitylene for 12 h gives mixed-sandwich [1-Cp-closo-1,2,3,4-FeP2CB8H9] ( 2) ( yield 63%). Reaction of the PPh4+ salt of the isomeric [nido-7,8,10-P2CB8H9](-) anion 3(-) with [CpFe(CO)(2)I] in refluxing mesitylene gives [1-Cp-closo-1,2,3,5-FeP2CB8H9] (4) (yield 56%), isomeric with 2. Compound 4 also results (yield 92%) from the sublimation of 2 under argon at ca. 350degreesC. The constitution of all compounds is established by mass spectrometry, IR spectroscopy and multinuclear NMR spectroscopy (H-1, B-11, P-31, and C-13; two-dimensional [B-11-B-11]-COSY, and H-1-{B-11(selective)), further confirmed in the case of 4 by a single-crystal X-ray diffraction analysis. (en) Difosfakarbollidová analoga ferrocenu: Syntéza dvou izomerních dvanácti-vrcholových closo-[(eta(5)-C5H5)FeP2CB8H9] komplexů. (cs)
Title	Diphosphacarborane analogues of ferrocene: The synthesis of two isomeric twelve-vertex closo-[(eta(5)-C5H5)FeP2CB8H9] complexes Difosfakarbollidová analoga ferrocenu: Syntéza dvou izomerních dvanácti-vrcholových closo-[(eta(5)-C5H5)FeP2CB8H9] komplexů (cs) Diphosphacarborane analogues of ferrocene: The synthesis of two isomeric twelve-vertex closo-[(eta(5)-C5H5)FeP2CB8H9] complexes (en)
skos:prefLabel	Diphosphacarborane analogues of ferrocene: The synthesis of two isomeric twelve-vertex closo-[(eta(5)-C5H5)FeP2CB8H9] complexes Difosfakarbollidová analoga ferrocenu: Syntéza dvou izomerních dvanácti-vrcholových closo-[(eta(5)-C5H5)FeP2CB8H9] komplexů (cs) Diphosphacarborane analogues of ferrocene: The synthesis of two isomeric twelve-vertex closo-[(eta(5)-C5H5)FeP2CB8H9] complexes (en)
skos:notation	RIV/61388980:_____/05:00029790!RIV06-AV0-61388980
http://linked.open.../vavai/riv/strany	909;913
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/05/2646), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Holub, Josef Štíbr, Bohumil Bakardjiev, Mario
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	518192
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/05:00029790
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	magnetic-resonance spectroscopy; phosphacarborane chemistry (en)
http://linked.open.../riv/klicoveSlovo	magnetic-resonance spectroscopy phosphacarborane chemistry
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[C572F533530E]
http://linked.open...i/riv/nazevZdroje	Dalton Transactions: an international journal of inorganic chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Derivatization of ferratricarbollide
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	-
http://linked.open...iv/tvurceVysledku	Bakardjiev, Mario Holub, Josef Štíbr, Bohumil Kennedy, D. J. Carr, M. J.
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	1477-9226
number of pages	5 (xsd:int)

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