About: Ferra- and ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11     Goto   Sponge   NotDistinct   Permalink

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Description
  • Ferra a ruthenatrikarbollidy CpFeC3B8H11 a Cp*RuC3B8H11byly připraveny insercí fragmentů CpFe+ a CpRu+ do skeletu trikarbaboranového aniontu [nido-7,8,9- C3B8H11]- . Je popsán i vznik několika isomerů lišících se polohou uhlíkových atomů ve skeletu. (cs)
  • The room-temperature photochemical reaction of the tricarbollide anion [nido-7,8,9-C3B8H11](-) (1a) with [CpFe(C6H6)](+) proceeds without cluster rearrangement to form the 12-vertex closo-ferratricarbollide 1-Cp-1,2,3,4-FeC3B8H11 (2a, the metal atom is assigned number 1). 2a rearranges to the isomeric complex 1-Cp-1,2,3,5-FeC3B8H11 (2b) at 110 degrees C and further to 1-Cp-1,2,4,10-FeC3B8H11 (2c) at 165 degrees C. The reaction of 1a with [Cp*RuCl](4) is accompanied by polyhedral rearrangement giving 1-Cp*-1,2,3,5-RuC3B8H11 (3b). The constitution of the compounds prepared was determined by multinuclear NMR spectroscopy and mass spectrometry. The structures of 2a, 2b, and 3c were established by X-ray diffraction.
  • The room-temperature photochemical reaction of the tricarbollide anion [nido-7,8,9-C3B8H11](-) (1a) with [CpFe(C6H6)](+) proceeds without cluster rearrangement to form the 12-vertex closo-ferratricarbollide 1-Cp-1,2,3,4-FeC3B8H11 (2a, the metal atom is assigned number 1). 2a rearranges to the isomeric complex 1-Cp-1,2,3,5-FeC3B8H11 (2b) at 110 degrees C and further to 1-Cp-1,2,4,10-FeC3B8H11 (2c) at 165 degrees C. The reaction of 1a with [Cp*RuCl](4) is accompanied by polyhedral rearrangement giving 1-Cp*-1,2,3,5-RuC3B8H11 (3b). The constitution of the compounds prepared was determined by multinuclear NMR spectroscopy and mass spectrometry. The structures of 2a, 2b, and 3c were established by X-ray diffraction. (en)
Title
  • Ferra- and ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11
  • Ferra a ruthenatrikarbollidy CpFeC3B8H11 a Cp*RuC3B8H11 (cs)
  • Ferra- and ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11 (en)
skos:prefLabel
  • Ferra- and ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11
  • Ferra a ruthenatrikarbollidy CpFeC3B8H11 a Cp*RuC3B8H11 (cs)
  • Ferra- and ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11 (en)
skos:notation
  • RIV/61388980:_____/05:00028598!RIV06-GA0-61388980
http://linked.open.../vavai/riv/strany
  • 4387;4392
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/05/2646)
http://linked.open...iv/cisloPeriodika
  • 18
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 521540
http://linked.open...ai/riv/idVysledku
  • RIV/61388980:_____/05:00028598
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • magnetic-resonance spectroscopy; metallatricarbadecaboranyl analogs; structural characterizations (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [DE6D1A486E99]
http://linked.open...i/riv/nazevZdroje
  • Organometallics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 24
http://linked.open...iv/tvurceVysledku
  • Holub, Josef
  • Štíbr, Bohumil
  • Kudinov, A. R.
  • Petrovskii, P. V.
  • Perelakin, D. S.
  • Golovanov, D. G.
  • Lyssenko, K. A.
issn
  • 0276-7333
number of pages
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