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Description
| - Ferra a ruthenatrikarbollidy CpFeC3B8H11 a Cp*RuC3B8H11byly připraveny insercí fragmentů CpFe+ a CpRu+ do skeletu trikarbaboranového aniontu [nido-7,8,9- C3B8H11]- . Je popsán i vznik několika isomerů lišících se polohou uhlíkových atomů ve skeletu. (cs)
- The room-temperature photochemical reaction of the tricarbollide anion [nido-7,8,9-C3B8H11](-) (1a) with [CpFe(C6H6)](+) proceeds without cluster rearrangement to form the 12-vertex closo-ferratricarbollide 1-Cp-1,2,3,4-FeC3B8H11 (2a, the metal atom is assigned number 1). 2a rearranges to the isomeric complex 1-Cp-1,2,3,5-FeC3B8H11 (2b) at 110 degrees C and further to 1-Cp-1,2,4,10-FeC3B8H11 (2c) at 165 degrees C. The reaction of 1a with [Cp*RuCl](4) is accompanied by polyhedral rearrangement giving 1-Cp*-1,2,3,5-RuC3B8H11 (3b). The constitution of the compounds prepared was determined by multinuclear NMR spectroscopy and mass spectrometry. The structures of 2a, 2b, and 3c were established by X-ray diffraction.
- The room-temperature photochemical reaction of the tricarbollide anion [nido-7,8,9-C3B8H11](-) (1a) with [CpFe(C6H6)](+) proceeds without cluster rearrangement to form the 12-vertex closo-ferratricarbollide 1-Cp-1,2,3,4-FeC3B8H11 (2a, the metal atom is assigned number 1). 2a rearranges to the isomeric complex 1-Cp-1,2,3,5-FeC3B8H11 (2b) at 110 degrees C and further to 1-Cp-1,2,4,10-FeC3B8H11 (2c) at 165 degrees C. The reaction of 1a with [Cp*RuCl](4) is accompanied by polyhedral rearrangement giving 1-Cp*-1,2,3,5-RuC3B8H11 (3b). The constitution of the compounds prepared was determined by multinuclear NMR spectroscopy and mass spectrometry. The structures of 2a, 2b, and 3c were established by X-ray diffraction. (en)
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Title
| - Ferra- and ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11
- Ferra a ruthenatrikarbollidy CpFeC3B8H11 a Cp*RuC3B8H11 (cs)
- Ferra- and ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11 (en)
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skos:prefLabel
| - Ferra- and ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11
- Ferra a ruthenatrikarbollidy CpFeC3B8H11 a Cp*RuC3B8H11 (cs)
- Ferra- and ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11 (en)
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skos:notation
| - RIV/61388980:_____/05:00028598!RIV06-GA0-61388980
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388980:_____/05:00028598
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - magnetic-resonance spectroscopy; metallatricarbadecaboranyl analogs; structural characterizations (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Holub, Josef
- Štíbr, Bohumil
- Kudinov, A. R.
- Petrovskii, P. V.
- Perelakin, D. S.
- Golovanov, D. G.
- Lyssenko, K. A.
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issn
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number of pages
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