About: Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene: New developments

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Ve formě přehledného referátu jsou diskutovány nové výsledky v chemii klastrových boranových analogů cyklopentadienylového aniontu a ferrocenu, které obsahují trikarbaboranové a fosfakarboranové sloučeniny jako ligandy. (cs) A review on cluster-borane analogues of the cyclopentadienide anion (Cp) and ferrocene is presented. Analogues of Cp that have been so far isolated and characterised are the 11-vertex triheteroboranes of general structure [nido-E3B8H8](-) (where E = CH or P and their combinations, the molecules of which contain an open pentagonal face. These anions were used as effective ligands for the preparation of %22half- and full-sandwich%22 complexes [CpFeE3B8H8] and [Fe(E3B8H8)(2)], respectively - analogues of ferrocene. Developments in this area of cluster-borane chemistry that include recent results in the synthesis and Fe-complexation reactions of 11-vertex tricarbaboranes (tricarbollides), phosphadicarbollides, and diphosphacarbollides are the subject of this work. A review on cluster-borane analogues of the cyclopentadienide anion (Cp) and ferrocene is presented. Analogues of Cp that have been so far isolated and characterised are the 11-vertex triheteroboranes of general structure [nido-E3B8H8](-) (where E = CH or P and their combinations, the molecules of which contain an open pentagonal face. These anions were used as effective ligands for the preparation of %22half- and full-sandwich%22 complexes [CpFeE3B8H8] and [Fe(E3B8H8)(2)], respectively - analogues of ferrocene. Developments in this area of cluster-borane chemistry that include recent results in the synthesis and Fe-complexation reactions of 11-vertex tricarbaboranes (tricarbollides), phosphadicarbollides, and diphosphacarbollides are the subject of this work. (en)
Title	Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene: New developments Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene: New developments (en) Nový vývoj chemie klastrových boranových analogů cyklopentadienylového aniontu a ferrocenu (cs)
skos:prefLabel	Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene: New developments Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene: New developments (en) Nový vývoj chemie klastrových boranových analogů cyklopentadienylového aniontu a ferrocenu (cs)
skos:notation	RIV/61388980:_____/05:00021607!RIV06-AV0-61388980
http://linked.open.../vavai/riv/strany	2694;2700
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/05/2646), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	11
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Štíbr, Bohumil
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	515180
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/05:00021607
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	boron; boranes; carboranes (en)
http://linked.open.../riv/klicoveSlovo	boranes carboranes boron
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[7FC1BDA4EB4E]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	1 (xsd:int)
http://linked.open...vavai/riv/projekt	Derivatization of ferratricarbollide
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	690
http://linked.open...iv/tvurceVysledku	Štíbr, Bohumil
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	0022-328X
number of pages	7 (xsd:int)

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