About: Diphosphacarbollide analogues of the (C5H5)- anion: Isolation of the nido-Di- and triphosphacarboranes 7, 8, 9-P2CB8H10, [7,8,9-P2CB8H9](-), [7,8,10-P2CB8H9](-), and 7,8,9,10-P3CB7H8

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About: Diphosphacarbollide analogues of the (C5H5)- anion: Isolation of the nido-Di- and triphosphacarboranes 7, 8, 9-P2CB8H10, [7,8,9-P2CB8H9](-), [7,8,10-P2CB8H9](-), and 7,8,9,10-P3CB7H8 Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Reakce mezi PCl3 and PS (PS = %22protonová houba%22 = 1,8-bis-dimethylaminonaftalen) a monokarbaboranem arachno-4-CB8H14 vedla k isolaci jedenáctivrcholových fosfakarboranů nido-7,8,9-P2CB8H10 a nido-7,8,9,10-P3CB7H8. Jsou diskutovány i některé základní reakce těchto sloučenin. (cs) Treatment of a solution of excess PCl3 and PS (PS = %22proton sponge%22 = 1,8-dimethylamino naphthalene) with arachno-4-CB8H14 (1) in CH2Cl2, followed by hydrolysis of the reaction mixture, resulted in the isolation of the eleven-vertex diphosphacarbaborane nido-7,8,9-P2CB8H10 (2) (yield 34percent) as the main product. Other products isolated from this reaction were the phosphacarboranes nido-7,8,9,10-P3CB7H8 (3) (yield 5percent) and closo-2,1-PCB8H9 (4) (yield 15percent). Compound 2 can be deprotonated by PS in CH2O2 or NaH in diethyl ether to give the [nido-7,8,9-P2CB8H9](-) (2(-)) anion, which gives back the original compound, 2, upon re-protonation. Treatment of a solution of excess PCl3 and PS (PS = %22proton sponge%22 = 1,8-dimethylamino naphthalene) with arachno-4-CB8H14 (1) in CH2Cl2, followed by hydrolysis of the reaction mixture, resulted in the isolation of the eleven-vertex diphosphacarbaborane nido-7,8,9-P2CB8H10 (2) (yield 34percent) as the main product. Other products isolated from this reaction were the phosphacarboranes nido-7,8,9,10-P3CB7H8 (3) (yield 5percent) and closo-2,1-PCB8H9 (4) (yield 15percent). Compound 2 can be deprotonated by PS in CH2O2 or NaH in diethyl ether to give the [nido-7,8,9-P2CB8H9](-) (2(-)) anion, which gives back the original compound, 2, upon re-protonation. (en)
Title	Diphosphacarbollide analogues of the (C5H5)- anion: Isolation of the nido-Di- and triphosphacarboranes 7, 8, 9-P2CB8H10, [7,8,9-P2CB8H9](-), [7,8,10-P2CB8H9](-), and 7,8,9,10-P3CB7H8 Difosfakarbollidová analoga (C5H5)- aniontu: Isolace nido di-a trifosphakarboranů 7,8,9-P2CB8H10, [7,8,9-P2CB8H9](-), [7,8,10-P2CB8H9](-), and 7,8,9,10-P3CB7H8 (cs) Diphosphacarbollide analogues of the (C5H5)- anion: Isolation of the nido-Di- and triphosphacarboranes 7, 8, 9-P2CB8H10, [7,8,9-P2CB8H9](-), [7,8,10-P2CB8H9](-), and 7,8,9,10-P3CB7H8 (en)
skos:prefLabel	Diphosphacarbollide analogues of the (C5H5)- anion: Isolation of the nido-Di- and triphosphacarboranes 7, 8, 9-P2CB8H10, [7,8,9-P2CB8H9](-), [7,8,10-P2CB8H9](-), and 7,8,9,10-P3CB7H8 Difosfakarbollidová analoga (C5H5)- aniontu: Isolace nido di-a trifosphakarboranů 7,8,9-P2CB8H10, [7,8,9-P2CB8H9](-), [7,8,10-P2CB8H9](-), and 7,8,9,10-P3CB7H8 (cs) Diphosphacarbollide analogues of the (C5H5)- anion: Isolation of the nido-Di- and triphosphacarboranes 7, 8, 9-P2CB8H10, [7,8,9-P2CB8H9](-), [7,8,10-P2CB8H9](-), and 7,8,9,10-P3CB7H8 (en)
skos:notation	RIV/61388980:_____/05:00021491!RIV06-AV0-61388980
http://linked.open.../vavai/riv/strany	5826;5832
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/05/2646), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	16
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Holub, Josef Štíbr, Bohumil Bakardjiev, Mario Hnyk, Drahomír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	518191
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/05:00021491
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	phosphacarboranes; spin Coupling constants (en)
http://linked.open.../riv/klicoveSlovo	spin Coupling constants phosphacarboranes
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[36DD6DC3200E]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Derivatization of ferratricarbollide
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	44
http://linked.open...iv/tvurceVysledku	Bakardjiev, Mario Holub, Josef Štíbr, Bohumil Hnyk, Drahomír Wrackmeyer, B.
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	0020-1669
number of pages	7 (xsd:int)

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