About: Macropolyhedral borane reaction chemistry: Reductive oligomerisation of (BuNC)-Bu-ter by anti-B18H22 to give the boron-coordinated {((BuNHCH)-Bu-ter) {(BuNHC)-Bu-ter)CN)}CH2:} carbene residue

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About: Macropolyhedral borane reaction chemistry: Reductive oligomerisation of (BuNC)-Bu-ter by anti-B18H22 to give the boron-coordinated {((BuNHCH)-Bu-ter) {(BuNHC)-Bu-ter)CN)}CH2:} carbene residue Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Reaction of (BuNC)-Bu-ter with anti-B18H22 in CH2ClCH2Cl gives [7-{((BuNHCH)-Bu-ter){(BuNHC)-Bu-ter(CN)}CH2}-anti-B18H20] in which a reductive oligomerisation of the (BuNC)-Bu-ter residues has given the complex polynitrogen base {((BuNHCH)-Bu-ter){(BuNHC)-Bu-ter(CN)}CH2:}, formally as a zwitterionic carbene attached to the macropolyhedral {B18H20} cluster. Reaction of (BuNC)-Bu-ter with anti-B18H22 in CH2ClCH2Cl gives [7-{((BuNHCH)-Bu-ter){(BuNHC)-Bu-ter(CN)}CH2}-anti-B18H20] in which a reductive oligomerisation of the (BuNC)-Bu-ter residues has given the complex polynitrogen base {((BuNHCH)-Bu-ter){(BuNHC)-Bu-ter(CN)}CH2:}, formally as a zwitterionic carbene attached to the macropolyhedral {B18H20} cluster. (en) Je popsána neobvyklá reduktivní oligomerace isonitrilového ligandu při reakci mezi terBuNC a anti-B18H22. (cs)
Title	Macropolyhedral borane reaction chemistry: Reductive oligomerisation of (BuNC)-Bu-ter by anti-B18H22 to give the boron-coordinated {((BuNHCH)-Bu-ter) {(BuNHC)-Bu-ter)CN)}CH2:} carbene residue Makropolyedrická klastrová borová chemie. Reduktivní oligomerace terBuNC pomocí anti-B18H22 za vzniku B-koordinovaného karbenového residua {( terBuNHCH){ terBuNHC(CN)CH2:} (cs) Macropolyhedral borane reaction chemistry: Reductive oligomerisation of (BuNC)-Bu-ter by anti-B18H22 to give the boron-coordinated {((BuNHCH)-Bu-ter) {(BuNHC)-Bu-ter)CN)}CH2:} carbene residue (en)
skos:prefLabel	Macropolyhedral borane reaction chemistry: Reductive oligomerisation of (BuNC)-Bu-ter by anti-B18H22 to give the boron-coordinated {((BuNHCH)-Bu-ter) {(BuNHC)-Bu-ter)CN)}CH2:} carbene residue Makropolyedrická klastrová borová chemie. Reduktivní oligomerace terBuNC pomocí anti-B18H22 za vzniku B-koordinovaného karbenového residua {( terBuNHCH){ terBuNHC(CN)CH2:} (cs) Macropolyhedral borane reaction chemistry: Reductive oligomerisation of (BuNC)-Bu-ter by anti-B18H22 to give the boron-coordinated {((BuNHCH)-Bu-ter) {(BuNHC)-Bu-ter)CN)}CH2:} carbene residue (en)
skos:notation	RIV/61388980:_____/05:00021201!RIV06-AV0-61388980
http://linked.open.../vavai/riv/strany	491;494
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/00/1042), P(GA203/05/2646), P(IAA4032701), P(LC523), Z(AV0Z40320502)
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Jelínek, Tomáš Štíbr, Bohumil
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	528566
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/05:00021201
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	borane cluster; X-ray structure; NMR spectroscopy (en)
http://linked.open.../riv/klicoveSlovo	NMR spectroscopy X-ray structure borane cluster
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[90A0EC471F21]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry Communications
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Perspective inorganic materials Metal complexation reactions of 9-11 vertex tricarba-, tetracarba- and carbaheteroborane ligands leading to metallaborane clusters with low boron content Derivatization of ferratricarbollide Fused-Cage Macropolyhedra Boranes, Carboranes, Heteroboranes, and Metallaheteroboranes.
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	8
http://linked.open...iv/tvurceVysledku	Jelínek, Tomáš Kennedy, J. D. Štíbr, Bohumil Kilner, C. A. Thornton-Pett, M. Barrett, S. A.
http://linked.open...n/vavai/riv/zamer	Design, syntéza a charakterizace klastrů, kompozitů, komplexů a dalších sloučenin na bázi anorganických látek; mechanismy a kinetika jejich interakcí
issn	1387-7003
number of pages	4 (xsd:int)

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