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  • Na základě teorie náhodné procházky byla odvozena distribuce a střední hodnota fluktuace o délce 2r kroků. Tyto výsledky byly kombinovány s exponenciálním rozdělením délky fluktuací ve spojité časové škále a s poissonovským rozdělením počtu reakčních událostí ve fixním časovém intervalu. Výsledky ukázaly, že tuto aproximaci lze použít i pro Ehrenfestův model rovnováhy. (cs)
  • On the bases of the random walk model, the distribution a mean of the amplitudes for a fluctuation of the lifetime 2r steps was derived. These results were combined with exponential distribution of fluctuations lifetime and with the Poisson distribution of the number of reaction events in fixed time interval. The results show that the random walk approximation can be used for the Ehrenfest model of chemical equilibrium.
  • On the bases of the random walk model, the distribution a mean of the amplitudes for a fluctuation of the lifetime 2r steps was derived. These results were combined with exponential distribution of fluctuations lifetime and with the Poisson distribution of the number of reaction events in fixed time interval. The results show that the random walk approximation can be used for the Ehrenfest model of chemical equilibrium. (en)
Title
  • Amplitudes of composition fluctuations in the simplest chemical reaction equilibrium
  • Amplitudes of composition fluctuations in the simplest chemical reaction equilibrium (en)
  • Amplitudy fluktuací složení v rovnováze nejjednodušší chemické reakce (cs)
skos:prefLabel
  • Amplitudes of composition fluctuations in the simplest chemical reaction equilibrium
  • Amplitudes of composition fluctuations in the simplest chemical reaction equilibrium (en)
  • Amplitudy fluktuací složení v rovnováze nejjednodušší chemické reakce (cs)
skos:notation
  • RIV/61388980:_____/04:00106533!RIV/2005/AV0/A50005/N
http://linked.open.../vavai/riv/strany
  • 1033;1040
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  • P(IAA4032101), Z(AV0Z4032918)
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  • 9
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  • 554034
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  • RIV/61388980:_____/04:00106533
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  • equilibrium composition fluctuations; Stochastic model; random walk (en)
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  • DE - Spolková republika Německo
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  • [F0DAA98695F8]
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  • Zeitschrift fur Physicalische Chemie -International Journal of Research in Physical Chemistry & Chemical Physic
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  • 218
http://linked.open...iv/tvurceVysledku
  • Hostomský, Jiří
  • Šolc, Milan
http://linked.open...n/vavai/riv/zamer
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  • 0942-9352
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