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| rdf:type
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| Description
| - Článek popisuje tvorbu matallokarboranů uvedených v titulu článku společně s popisem metallokarboranu nesoucího málo se vyskytující Rh-H-Rh můstkový vodikový atom. (cs)
- Reaction of the tetramethyl ammonium salt of the hypho-[6,7-C2B6H13](-) anion (1) with the [Rh(eta(5)-C5Me5)Cl-2](2) dimer in THF solution, resulted in the formation of a novel nine-vertex metalladicarbaborane [5-Cp*-arachno-5,4,6-RhC2B6H12](2) (Cp* = eta(5)-C5Me5). An analogous reaction, but in the presence of PS (PS='proton-sponge'=1,8-bis-(dimethylamino)-naphthalene), resulted in the bimetallic nine-vertex species [2,5-Cp*(2)-10-Me-nido-2,5,1-Rh2CB6H9] (3). Compounds 2 and 3 are structural analogues of carboranes arachno-4,6-C2B7H13 (4) and nido-1-CB8H12 (5), respectively. The formation of compound 3 is associated with an extrusion of one of the cluster carbon atoms into an exo-polyhedral position and exhibits a very rare nine-vertex nido metallaborane structure with interesting features. Both species 2 and 3 were characterized by multinuclear NMR measurements and single-crystal X-ray diffraction studies.
- Reaction of the tetramethyl ammonium salt of the hypho-[6,7-C2B6H13](-) anion (1) with the [Rh(eta(5)-C5Me5)Cl-2](2) dimer in THF solution, resulted in the formation of a novel nine-vertex metalladicarbaborane [5-Cp*-arachno-5,4,6-RhC2B6H12](2) (Cp* = eta(5)-C5Me5). An analogous reaction, but in the presence of PS (PS='proton-sponge'=1,8-bis-(dimethylamino)-naphthalene), resulted in the bimetallic nine-vertex species [2,5-Cp*(2)-10-Me-nido-2,5,1-Rh2CB6H9] (3). Compounds 2 and 3 are structural analogues of carboranes arachno-4,6-C2B7H13 (4) and nido-1-CB8H12 (5), respectively. The formation of compound 3 is associated with an extrusion of one of the cluster carbon atoms into an exo-polyhedral position and exhibits a very rare nine-vertex nido metallaborane structure with interesting features. Both species 2 and 3 were characterized by multinuclear NMR measurements and single-crystal X-ray diffraction studies. (en)
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| Title
| - Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a...
- Metallakarboránová chemie aniontu hypho-[6,7-C2B6H13](-) : příprava nových metallakarboránů s jedinečnými strukturami [5-Cp*-arachno-5,4,6-RhC2B6H12] a [2,5-(Cp*)2-10-Me-nido-2,5,1-Rh2CB6H9 : úplná rhodiová analoga arachno-4,6-C2B7H13 a nido-1-CB8H12 (cs)
- Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a... (en)
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| skos:prefLabel
| - Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a...
- Metallakarboránová chemie aniontu hypho-[6,7-C2B6H13](-) : příprava nových metallakarboránů s jedinečnými strukturami [5-Cp*-arachno-5,4,6-RhC2B6H12] a [2,5-(Cp*)2-10-Me-nido-2,5,1-Rh2CB6H9 : úplná rhodiová analoga arachno-4,6-C2B7H13 a nido-1-CB8H12 (cs)
- Metallacarborane chemistry of the hypho-[6,7-C2B6H13](-)1-anion: the formation of uniquely structured metallacarboranes [5-Cp*-arachno-5,4,6-RhC2B6H12] and [2,5-Cp-2(*)-10-Me-nido-2,5,1-Rh2CB6H9] (Cp-* = eta(5)-C5Me5-): complete rhodium analogues of a... (en)
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| skos:notation
| - RIV/61388980:_____/04:00106529!RIV/2005/AV0/A50005/N
|
| http://linked.open.../vavai/riv/strany
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
| - P(LN00A028), Z(AV0Z4032918)
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| http://linked.open...iv/cisloPeriodika
| |
| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388980:_____/04:00106529
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - boranes; metallacarboranes; rhodium complex (en)
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| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Journal of Organometalic Chemistry
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Císařová, I.
- Londesborough, Michael Geoffrey Stephen
- Štíbr, Bohumil
- Janoušek, Zbyněk
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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