About: Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series.

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About: Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Treatment of the [2-Cp-9tBuNH-closo-2,1,7,9-FeC3B8H10] (1) ferratricarbollide (Cp = eta(5)-C5H5-) with Na+C10H8- in 1,2-dimethoxy-ethane (DME) at room temperature produced an air-sensitive transient anion with a tentatively identified nido-[tBuNH-CpFeC3B8H10](2-) constitution. In-situ reaction of this low-stability ion with [CpFe(CO)(2)I] or [CpFe(CO)(2)](2) generated three violet di-ferratricarbaboranes identified as paramagnetic subcloso complexes [4,5-Cp2--4,5,1,6,7-Fe2C3B8H11] (2; yield 2%), [4,5-CP2--4,5,1,7,12-Fe2C3B8H11] (3; yield 2%), and [7-tBuNH-4,5-Cp2-- 4,5,1,7,12-Fe2C3B8H10] (4; yield 14%). These first representatives of the 13-vertex dimetallatricarbaborane family were characterized by EPR and IR spectroscopy, and mass spectrometry, and their structures were determined by X-ray diffraction analysis. Treatment of the [2-Cp-9tBuNH-closo-2,1,7,9-FeC3B8H10] (1) ferratricarbollide (Cp = eta(5)-C5H5-) with Na+C10H8- in 1,2-dimethoxy-ethane (DME) at room temperature produced an air-sensitive transient anion with a tentatively identified nido-[tBuNH-CpFeC3B8H10](2-) constitution. In-situ reaction of this low-stability ion with [CpFe(CO)(2)I] or [CpFe(CO)(2)](2) generated three violet di-ferratricarbaboranes identified as paramagnetic subcloso complexes [4,5-Cp2--4,5,1,6,7-Fe2C3B8H11] (2; yield 2%), [4,5-CP2--4,5,1,7,12-Fe2C3B8H11] (3; yield 2%), and [7-tBuNH-4,5-Cp2-- 4,5,1,7,12-Fe2C3B8H10] (4; yield 14%). These first representatives of the 13-vertex dimetallatricarbaborane family were characterized by EPR and IR spectroscopy, and mass spectrometry, and their structures were determined by X-ray diffraction analysis. (en)
Title	Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series. Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series. (en)
skos:prefLabel	Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series. Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series. (en)
skos:notation	RIV/61388980:_____/03:50033041!RIV/2004/MSM/A50004/N
http://linked.open.../vavai/riv/strany	6115;6121
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/00/1042), P(GA203/01/0944), P(LN00A028), Z(AV0Z4032918)
http://linked.open...iv/cisloPeriodika	24
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Štíbr, Bohumil Stopka, Pavel Grüner, Bohumír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	603813
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/03:50033041
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	boranes; carboranes; cluster compounds (en)
http://linked.open.../riv/klicoveSlovo	boranes carboranes cluster compounds
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[E2BDEE841A12]
http://linked.open...i/riv/nazevZdroje	Chemistry A European Journal
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	New inorganic compounds and advanced materials Metal complexation reactions of 9-11 vertex tricarba-, tetracarba- and carbaheteroborane ligands leading to metallaborane clusters with low boron content Prepration and reactions of oxygen-ozone mixtures. Applications to chemistry, medicine and ecology
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	9
http://linked.open...iv/tvurceVysledku	Grüner, Bohumír Stopka, Pavel Štíbr, Bohumil Teixidor, F. Kivekäs, R. Sillanpää, R. Vinas, C.
http://linked.open...n/vavai/riv/zamer	Synthesis and structure of novel (inorganic) compounds, clusters and composites; mechanisms of conversion and transfer in systems involving inorganic substance
issn	0947-6539
number of pages	7 (xsd:int)

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