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rdf:type
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Description
| - The reaction between excess n-C4H9ONO and arachno-4,5-C2B7H13 (1) in diethyl ether at room temperature results in the formation of the first representatives of the arachno ten-vertex azadicarbaborane family, arachno-6,5,9-NC2B7H12 (2) and arachno-6,5,10-NC2B7H12 (3) in yields of 6 and 20%, respectively. The reaction also generates exo-8-CH3-hypho-7,8-NCB6H11 (4) (yield 5%) as a result of the extrusion of the CH2 group from the cluster of the starting dicarbaborane to generate a terminal methyl unit. The reaction between 8,9-mu-NH2-arachno-5,6-C2B8H11 (5) and NaH, followed by treatment with iodine and water, produced the unique endo isomer of 4, endo-8-CH3- hypho-7,8-NCB6H11 (6) (yield 22%). The reaction between n-C4H9ONO and nido-5,6-C2B8H12 (7) in hexane at reflux generates the first compound of the ten-vertex nido azadicarbaborane family, nido-6,8,9-C2NB7H10 (8), in 13% yield. The structures of all the compounds isolated are proposed on the basis of NMR spectroscopy, the geometries optimized at the
- The reaction between excess n-C4H9ONO and arachno-4,5-C2B7H13 (1) in diethyl ether at room temperature results in the formation of the first representatives of the arachno ten-vertex azadicarbaborane family, arachno-6,5,9-NC2B7H12 (2) and arachno-6,5,10-NC2B7H12 (3) in yields of 6 and 20%, respectively. The reaction also generates exo-8-CH3-hypho-7,8-NCB6H11 (4) (yield 5%) as a result of the extrusion of the CH2 group from the cluster of the starting dicarbaborane to generate a terminal methyl unit. The reaction between 8,9-mu-NH2-arachno-5,6-C2B8H11 (5) and NaH, followed by treatment with iodine and water, produced the unique endo isomer of 4, endo-8-CH3- hypho-7,8-NCB6H11 (6) (yield 22%). The reaction between n-C4H9ONO and nido-5,6-C2B8H12 (7) in hexane at reflux generates the first compound of the ten-vertex nido azadicarbaborane family, nido-6,8,9-C2NB7H10 (8), in 13% yield. The structures of all the compounds isolated are proposed on the basis of NMR spectroscopy, the geometries optimized at the (en)
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Title
| - Azacarbaborane chemistry. Butyl nitrite synthesis of the new eight-, nine- and ten-vertex azacarbaboranes exo- and endo-7-CH3-hypho-7,8-NCB6H11, nido-6,8,9-NC2B7H10, arachno-6,5,9-NC2B7H12 and arachno-6,5,10-C2NB7H12.
- Azacarbaborane chemistry. Butyl nitrite synthesis of the new eight-, nine- and ten-vertex azacarbaboranes exo- and endo-7-CH3-hypho-7,8-NCB6H11, nido-6,8,9-NC2B7H10, arachno-6,5,9-NC2B7H12 and arachno-6,5,10-C2NB7H12. (en)
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skos:prefLabel
| - Azacarbaborane chemistry. Butyl nitrite synthesis of the new eight-, nine- and ten-vertex azacarbaboranes exo- and endo-7-CH3-hypho-7,8-NCB6H11, nido-6,8,9-NC2B7H10, arachno-6,5,9-NC2B7H12 and arachno-6,5,10-C2NB7H12.
- Azacarbaborane chemistry. Butyl nitrite synthesis of the new eight-, nine- and ten-vertex azacarbaboranes exo- and endo-7-CH3-hypho-7,8-NCB6H11, nido-6,8,9-NC2B7H10, arachno-6,5,9-NC2B7H12 and arachno-6,5,10-C2NB7H12. (en)
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skos:notation
| - RIV/61388980:_____/03:50033019!RIV/2004/MSM/A50004/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(LN00A028), Z(AV0Z4032918)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388980:_____/03:50033019
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - structural characterizations; insertion reactions; chemical-shifts (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Jelínek, Tomáš
- Kennedy, J. D.
- Štíbr, Bohumil
- Hnyk, Drahomír
- Hofmann, M.
- Bühl, M.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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