About: Voltammetric identification of pedogenic iron oxides in paleosol and loess.     Goto   Sponge   NotDistinct   Permalink

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  • Voltammetry of immobilized microparticles was used to detect low concentrations of goethite and hematite in paleosol and loess samples. The total content of Fe oxides in the natural samples was below 2 wt% and below the detection limit of X-ray powder diffraction. Goethite was distinguished from hematite due to the different electrochemical reactivity of the product of thermal dehydroxylation of goethite (very fine crystalline hematite). The voltammetric analysis was tested using synthetic samples of ferrihydrite, goethite, hematite, magnetite, or Mg-ferrite with SiO2 and a natural sample of smectite with an admixture of goethite. The detection is most sensitive for goethite and hematite (detection limit about 0.1 wt%), and approximately an order of magnitude better than X-ray powder diffraction analysis.
  • Voltammetry of immobilized microparticles was used to detect low concentrations of goethite and hematite in paleosol and loess samples. The total content of Fe oxides in the natural samples was below 2 wt% and below the detection limit of X-ray powder diffraction. Goethite was distinguished from hematite due to the different electrochemical reactivity of the product of thermal dehydroxylation of goethite (very fine crystalline hematite). The voltammetric analysis was tested using synthetic samples of ferrihydrite, goethite, hematite, magnetite, or Mg-ferrite with SiO2 and a natural sample of smectite with an admixture of goethite. The detection is most sensitive for goethite and hematite (detection limit about 0.1 wt%), and approximately an order of magnitude better than X-ray powder diffraction analysis. (en)
Title
  • Voltammetric identification of pedogenic iron oxides in paleosol and loess.
  • Voltammetric identification of pedogenic iron oxides in paleosol and loess. (en)
skos:prefLabel
  • Voltammetric identification of pedogenic iron oxides in paleosol and loess.
  • Voltammetric identification of pedogenic iron oxides in paleosol and loess. (en)
skos:notation
  • RIV/61388980:_____/02:50023012!RIV/2003/AV0/A50003/N
http://linked.open.../vavai/riv/strany
  • 339;344
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z4032918)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 669385
http://linked.open...ai/riv/idVysledku
  • RIV/61388980:_____/02:50023012
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • goethite; hematite; paleosol (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [38380E2E84C6]
http://linked.open...i/riv/nazevZdroje
  • Electroanalyssis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 14
http://linked.open...iv/tvurceVysledku
  • Grygar, Tomáš
  • van Oorschot, I. H. M.
http://linked.open...n/vavai/riv/zamer
issn
  • 1040-0397
number of pages
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