About: Recent developments in the chemistry of the nine-vertex monocarbaboranes.

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A short review is presented on the routes to the synthesis of the nine-vertex monocarbaboranes arachno-4-CB8H14 and nido-1-CB8H12 12, which now have become very important starting materials for the preparation of a family of 'smaller-cage' seven-, eight-, and nine-vertex closo monocarbaborane anions [2-CB6H7](-), [1-CB7H8](-), and [4-CB8H9](-). These anions exhibit high stability and have a good chance to become new candidates for weakly coordinated anion chemistry. Discussed are also reactions leading new families of phosphamonocarbaboranes that contain one, two, and three phosphorus atoms in the cage. These compounds, namely closo-2,1-PCB8H9, closo-6,1-PCB8H9, nido-7,8,9-P2CB8H10, and nido-6,7,8,9,10-P3CB7H8, are structural analogues of the corresponding carboranes and are likely to exhibit similar chemical behavior. (C) 2002 Elsevier Science B.V. All rights reserved. A short review is presented on the routes to the synthesis of the nine-vertex monocarbaboranes arachno-4-CB8H14 and nido-1-CB8H12 12, which now have become very important starting materials for the preparation of a family of 'smaller-cage' seven-, eight-, and nine-vertex closo monocarbaborane anions [2-CB6H7](-), [1-CB7H8](-), and [4-CB8H9](-). These anions exhibit high stability and have a good chance to become new candidates for weakly coordinated anion chemistry. Discussed are also reactions leading new families of phosphamonocarbaboranes that contain one, two, and three phosphorus atoms in the cage. These compounds, namely closo-2,1-PCB8H9, closo-6,1-PCB8H9, nido-7,8,9-P2CB8H10, and nido-6,7,8,9,10-P3CB7H8, are structural analogues of the corresponding carboranes and are likely to exhibit similar chemical behavior. (C) 2002 Elsevier Science B.V. All rights reserved. (en)
Title	Recent developments in the chemistry of the nine-vertex monocarbaboranes. Recent developments in the chemistry of the nine-vertex monocarbaboranes. (en)
skos:prefLabel	Recent developments in the chemistry of the nine-vertex monocarbaboranes. Recent developments in the chemistry of the nine-vertex monocarbaboranes. (en)
skos:notation	RIV/61388980:_____/02:50023011!RIV/2003/AV0/A50003/N
http://linked.open.../vavai/riv/strany	3;8
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IBS4032007), P(LN00A028), Z(AV0Z4032918)
http://linked.open...iv/cisloPeriodika	1-2
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Štíbr, Bohumil
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav anorganické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	661605
http://linked.open...ai/riv/idVysledku	RIV/61388980:_____/02:50023011
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	boron clusters; carboranes; monocarbaboranes (en)
http://linked.open.../riv/klicoveSlovo	boron clusters carboranes monocarbaboranes
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[B5304122E1D5]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	New inorganic compounds and advanced materials Methodical centre for the development of new technological processes for the production of boron compounds
http://linked.open...UplatneniVysledku	2002
http://linked.open...v/svazekPeriodika	657
http://linked.open...iv/tvurceVysledku	Štíbr, Bohumil Wrackmeyer, B.
http://linked.open...n/vavai/riv/zamer	Synthesis and structure of novel (inorganic) compounds, clusters and composites; mechanisms of conversion and transfer in systems involving inorganic substance
issn	0022-328X
number of pages	6 (xsd:int)

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