About: Scanning electron microscopic imaging of surface effects in desorption and nano-desorption electrospray ionization     Goto   Sponge   NotDistinct   Permalink

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  • Scanning electron microscopy was used to investigate rivulets that are formed on the analyzed surface during desorption electrospray ionization (DESI) experiment. Ferromagnetic nanoparticles added to the spray solvent in a form of colloid solution functioned as an additional surface probe. The existence of the rivulets was confirmed on glass and newly demonstrated on two different types of porous PTFE. The results show that in standard DESI set-up the rivulets are arranged into very regular shapes. Same rivulets were obtained in DESI experiments without high voltage on the sprayer. However, no such rivulets or any other regular patterns were found on a surface in nano-DESI (nanospray DESI without the carrier nebulizing gas) experiments. This indicates that symmetrical rivulets are created by the hydrodynamical rather than electrostatic forces. It was also demonstrated that blocking the rivulets by a simple physical barrier did not influence known surface charging effects.
  • Scanning electron microscopy was used to investigate rivulets that are formed on the analyzed surface during desorption electrospray ionization (DESI) experiment. Ferromagnetic nanoparticles added to the spray solvent in a form of colloid solution functioned as an additional surface probe. The existence of the rivulets was confirmed on glass and newly demonstrated on two different types of porous PTFE. The results show that in standard DESI set-up the rivulets are arranged into very regular shapes. Same rivulets were obtained in DESI experiments without high voltage on the sprayer. However, no such rivulets or any other regular patterns were found on a surface in nano-DESI (nanospray DESI without the carrier nebulizing gas) experiments. This indicates that symmetrical rivulets are created by the hydrodynamical rather than electrostatic forces. It was also demonstrated that blocking the rivulets by a simple physical barrier did not influence known surface charging effects. (en)
Title
  • Scanning electron microscopic imaging of surface effects in desorption and nano-desorption electrospray ionization
  • Scanning electron microscopic imaging of surface effects in desorption and nano-desorption electrospray ionization (en)
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  • Scanning electron microscopic imaging of surface effects in desorption and nano-desorption electrospray ionization
  • Scanning electron microscopic imaging of surface effects in desorption and nano-desorption electrospray ionization (en)
skos:notation
  • RIV/61388971:_____/11:00363441!RIV12-AV0-61388971
http://linked.open...avai/riv/aktivita
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  • I, P(GPP206/10/P018), P(LC545), P(ME10013), S, Z(AV0Z40550506), Z(AV0Z50200510)
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  • 3
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  • 228211
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  • RIV/61388971:_____/11:00363441
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  • ionization; DESI; nano-DESI; electron microscopy; mass spectrometry (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [08837365277C]
http://linked.open...i/riv/nazevZdroje
  • Journal of Mass Spectrometry
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  • 46
http://linked.open...iv/tvurceVysledku
  • Benada, Oldřich
  • Cvačka, Josef
  • Lemr, Karel
  • Havlíček, Vladimír
  • Kaftan, Filip
  • Volný, Michael
  • Kofroňová, Olga
http://linked.open...ain/vavai/riv/wos
  • 000288463900003
http://linked.open...n/vavai/riv/zamer
issn
  • 1076-5174
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/jms.1888
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