About: Glycosides of arylnaphthalene lignans from Acanthus mollis having axial chirality

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About: Glycosides of arylnaphthalene lignans from Acanthus mollis having axial chirality Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Glycosides of arylnaphthalene lignans having axial chirality were isolated from Acanthus mollis. Owing to the axial chirality, their structure, including absolute configuration, was determined by means of extensive spectroscopic data such as UV, IR, MS, 1D and 2D NMR spectra, and computational chiroptical methods. A compound, 20,4-dihydroxyretrohelioxanthin (20-hydroxy-justirumalin), has a structure containing two aromatic moieties with substituents hindering rotation about the biaryl axis. The aglycone was connected to a saccharide moiety linked at C-4 or C-20 and made up of one or four sugars (rhamnose or quinovose, and tetrasaccharide 4-O-b-D-xylopyranosyl-(100000-600)-O-[b-D-rhamnopyranosyl-(10000-300)]-O-b-Dapiofuranosyl-(10000-200)-O-b-D-glucopyranoside and quinovose) Glycosides of arylnaphthalene lignans having axial chirality were isolated from Acanthus mollis. Owing to the axial chirality, their structure, including absolute configuration, was determined by means of extensive spectroscopic data such as UV, IR, MS, 1D and 2D NMR spectra, and computational chiroptical methods. A compound, 20,4-dihydroxyretrohelioxanthin (20-hydroxy-justirumalin), has a structure containing two aromatic moieties with substituents hindering rotation about the biaryl axis. The aglycone was connected to a saccharide moiety linked at C-4 or C-20 and made up of one or four sugars (rhamnose or quinovose, and tetrasaccharide 4-O-b-D-xylopyranosyl-(100000-600)-O-[b-D-rhamnopyranosyl-(10000-300)]-O-b-Dapiofuranosyl-(10000-200)-O-b-D-glucopyranoside and quinovose) (en)
Title	Glycosides of arylnaphthalene lignans from Acanthus mollis having axial chirality Glycosides of arylnaphthalene lignans from Acanthus mollis having axial chirality (en)
skos:prefLabel	Glycosides of arylnaphthalene lignans from Acanthus mollis having axial chirality Glycosides of arylnaphthalene lignans from Acanthus mollis having axial chirality (en)
skos:notation	RIV/61388971:_____/09:00327047!RIV10-MSM-61388971
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(1M06011), Z(AV0Z50200510)
http://linked.open...iv/cisloPeriodika	8
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Řezanka, Tomáš Sigler, Karel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Mikrobiologický ústav AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	316530
http://linked.open...ai/riv/idVysledku	RIV/61388971:_____/09:00327047
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	acanthus mollis; glycosides; cytotoxicity (en)
http://linked.open.../riv/klicoveSlovo	acanthus mollis cytotoxicity glycosides
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[6917A4B2AA1C]
http://linked.open...i/riv/nazevZdroje	Phytochemistry
http://linked.open...in/vavai/riv/obor	EE
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	The Centre of Molecular Methods for Monitoring the Diffuse Pollution of the Environment.
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	70
http://linked.open...iv/tvurceVysledku	Sigler, Karel Řezanka, Tomáš Řezanka,, P.
http://linked.open...ain/vavai/riv/wos	000268658700010
http://linked.open...n/vavai/riv/zamer	Microorganisms in Research and Biotechnology
issn	0031-9422
number of pages	6 (xsd:int)

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