About: Molecular shape selectivity of hydrotalcite in mixed aldol condensations of aldehydes and ketones

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About: Molecular shape selectivity of hydrotalcite in mixed aldol condensations of aldehydes and ketones Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Práce se zabývá vlivem aktivovaného hydrotalcitu na aldolovou kondenzaci cyklických a lineárních ketonů s n-heptanalem a norborn-5-en-2-karbaldehydem. Byla zjištěna významná konfigurační selektivita katalyzátoru, přičemž kondenzace cyklických ketonů byla preferována proti kondenzaci lineárních ketonů. Mechanismus povrchové reakce byl interpretován pomocí molekulárního modelování (cs) The work has engaged in the effect of activated hydrotalcite for aldol condensation of cyclic and linear ketones with n-heptanal and norborn-5-ene-2-carbaldehyde. A significant configuration selectivity of the catalyst was found, when the condensation of the cyclic ketones was strongly prefered in comparison with condensation of the linear ones. The mechanism of the surface reaction was predicted by the methods of molecular modeling The work has engaged in the effect of activated hydrotalcite for aldol condensation of cyclic and linear ketones with n-heptanal and norborn-5-ene-2-carbaldehyde. A significant configuration selectivity of the catalyst was found, when the condensation of the cyclic ketones was strongly prefered in comparison with condensation of the linear ones. The mechanism of the surface reaction was predicted by the methods of molecular modeling (en)
Title	Molecular shape selectivity of hydrotalcite in mixed aldol condensations of aldehydes and ketones Tvarová selektivita hydrotalcitů ve směsné aldolové kondenzaci aldehydů a ketonů (cs) Molecular shape selectivity of hydrotalcite in mixed aldol condensations of aldehydes and ketones (en)
skos:prefLabel	Molecular shape selectivity of hydrotalcite in mixed aldol condensations of aldehydes and ketones Tvarová selektivita hydrotalcitů ve směsné aldolové kondenzaci aldehydů a ketonů (cs) Molecular shape selectivity of hydrotalcite in mixed aldol condensations of aldehydes and ketones (en)
skos:notation	RIV/61388971:_____/08:00312946!RIV09-AV0-61388971
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA104/07/1239), Z(AV0Z50200510), Z(MSM6046137301)
http://linked.open...iv/cisloPeriodika	1-2
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Kuzma, Marek
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Mikrobiologický ústav AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	380352
http://linked.open...ai/riv/idVysledku	RIV/61388971:_____/08:00312946
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	hydrocalcite; aldol condensation; molecular modeling (en)
http://linked.open.../riv/klicoveSlovo	aldol condensation molecular modeling hydrocalcite
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[E4F70EEC9B5C]
http://linked.open...i/riv/nazevZdroje	Journal of Molecular Catalysis A-Chemical
http://linked.open...in/vavai/riv/obor	EE
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Modern aspects of partial hydrogenation of CC triple bond
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	285
http://linked.open...iv/tvurceVysledku	Kačer, P. Kuzma, Marek Červený, J. Kovanda, F. Červený, L. Šplíchalová, J.
http://linked.open...ain/vavai/riv/wos	000256178900020
http://linked.open...n/vavai/riv/zamer	Catalytic processes in chemistry and chemical technology Microorganisms in Research and Biotechnology
issn	1381-1169
number of pages	5 (xsd:int)

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