About: Separation of planar rotamers through intramolecular hydrogen bonding in polysubstituted 5-nitrosopyrimidines     Goto   Sponge   NotDistinct   Permalink

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Description
  • While purifying new polysubstituted 5-nitrosopyrimidines, the unique separation of pairs of rotamers as chemical species, stabilized by a single intramolecular hydrogen bond and differing only in nitroso group orientation, was achieved. This interesting stereochemical phenomenon is compared to the well-known atropisomerism.
  • While purifying new polysubstituted 5-nitrosopyrimidines, the unique separation of pairs of rotamers as chemical species, stabilized by a single intramolecular hydrogen bond and differing only in nitroso group orientation, was achieved. This interesting stereochemical phenomenon is compared to the well-known atropisomerism. (en)
Title
  • Separation of planar rotamers through intramolecular hydrogen bonding in polysubstituted 5-nitrosopyrimidines
  • Separation of planar rotamers through intramolecular hydrogen bonding in polysubstituted 5-nitrosopyrimidines (en)
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  • Separation of planar rotamers through intramolecular hydrogen bonding in polysubstituted 5-nitrosopyrimidines
  • Separation of planar rotamers through intramolecular hydrogen bonding in polysubstituted 5-nitrosopyrimidines (en)
skos:notation
  • RIV/61388963:_____/14:00435160!RIV15-MV0-61388963
http://linked.open...avai/riv/aktivita
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  • I, P(GA13-24880S), P(VG20102015046), S
http://linked.open...iv/cisloPeriodika
  • 94
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  • 44521
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  • RIV/61388963:_____/14:00435160
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  • hydrogen bonds; 5-nitrosopyrimidines; NMR spectroscopy (en)
http://linked.open.../riv/klicoveSlovo
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [A7518650AD8E]
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  • Chemical Communications
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  • 50
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  • Císařová, I.
  • Dračínský, Martin
  • Janeba, Zlatko
  • Čechová, Lucie
  • Procházková, Eliška
http://linked.open...ain/vavai/riv/wos
  • 000344460300048
issn
  • 1359-7345
number of pages
http://bibframe.org/vocab/doi
  • 10.1039/c4cc06978a
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