About: Azahelicene Superbases as MAILD Matrices for Acidic Analytes

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	1,14-Diaza[5]helicene can serve as a new, efficient MAILD matrix, outperforming other bases such as DMAN, and is highly suitable for high-throughput metabolomics analysis. Superiority of this compound stemmed from the constructive interplay of its high basicity, ability to absorb energy of UV-light laser pulses, and resistance to fragmentation and desorption. Experimental and computational data led us to discover a rationale for the ionisation processprocess: there is a correlation between the basicity (and proton-sponge character) of matrices and their efficacy in MAILD-MS. 1,14-Diaza[5]helicene can serve as a new, efficient MAILD matrix, outperforming other bases such as DMAN, and is highly suitable for high-throughput metabolomics analysis. Superiority of this compound stemmed from the constructive interplay of its high basicity, ability to absorb energy of UV-light laser pulses, and resistance to fragmentation and desorption. Experimental and computational data led us to discover a rationale for the ionisation processprocess: there is a correlation between the basicity (and proton-sponge character) of matrices and their efficacy in MAILD-MS. (en)
Title	Azahelicene Superbases as MAILD Matrices for Acidic Analytes Azahelicene Superbases as MAILD Matrices for Acidic Analytes (en)
skos:prefLabel	Azahelicene Superbases as MAILD Matrices for Acidic Analytes Azahelicene Superbases as MAILD Matrices for Acidic Analytes (en)
skos:notation	RIV/61388963:_____/13:00397464!RIV14-GA0-61388963
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GA203/09/1766), P(GAP206/12/0453), P(IAA400550916)
http://linked.open...iv/cisloPeriodika	9
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Rulíšek, Lubomír Klívar, Jiří Kašička, Václav Starý, Ivo Stará, Irena G. Jančařík, Andrej Šámal, Michal Šolínová, Veronika Svatoš, Aleš
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	62771
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/13:00397464
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	azahelicene superbases; MAILD-MS matrix; acidic analytes; matrix isolation; metabolomics (en)
http://linked.open.../riv/klicoveSlovo	MAILD-MS matrix acidic analytes azahelicene superbases matrix isolation metabolomics - metabolic profiling - metabolic %22fingerprint%22- medicinal plants
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[1429F35D596F]
http://linked.open...i/riv/nazevZdroje	ChemPlusChem
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	9 (xsd:int)
http://linked.open...cetTvurcuVysledku	10 (xsd:int)
http://linked.open...vavai/riv/projekt	Azahelicenes: Their Synthesis, Properties and Use Exploring Helically Chiral Ligands in Enantioselective Transition Metal Catalysis Affinity capillary electromigration methods for selective nanoanalysis of biomolecules and investigation of their interactions
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	78
http://linked.open...iv/tvurceVysledku	Kašička, Václav Rulíšek, Lubomír Stará, Irena G. Starý, Ivo Svatoš, Aleš Jančařík, Andrej Šámal, Michal Šolínová, Veronika Klívar, Jiří Napagoda, M.
http://linked.open...ain/vavai/riv/wos	000324043400011
issn	2192-6506
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/cplu.201300258

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