| Attributes | Values |
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| rdf:type
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| Description
| - The diimine compound 1-[(2',3',4',5'-tetraphenylbiphenyl-4-yl)methyl]-2-(pyridin-2-yl)-1H-benzo[d]imidazole (Ph6PyMz) has been designed and synthesized in order to prepare [Cu(Ph6PyMz)(DPEphos)]BF4 {DPEphos = bis[2-(diphenylphosphanyl)phenyl] ether} and [RePh6PyMz(CO)3Br]. The molecular structures of [Cu(Ph6PyMz)(DPEphos)]BF4 and [RePh6PyMz(CO)3Br] were determined by single-crystal X-ray diffraction and IR spectroscopy, and their properties were systematically studied by thermal-stability analyses, photophysical analyses, and electrochemistry. It was found that [Cu(Ph6PyMz)(DPEphos)]BF4 and [RePh6PyMz(CO)3Br] mainly give triplet-ligand-to-ligand charge-transfer transition emission in CH2Cl2 solution and pure triplet-metal-to-ligand charge-transfer transition emission in the solid state. The different photophysical behaviors of [Cu(Ph6PyMz)(DPEphos)]BF4 and [RePh6PyMz(CO)3Br] in different states has been attributed to solvent effects and their higher freedom in CH2Cl2 solution. The energy levels of the highest-occupied and lowest-unoccupied molecular orbitals were measured to be 5.76 and 3.11 eV for [Cu(Ph6PyMz)(DPEphos)]BF4 and 5.69 and 3.42 eV for [RePh6PyMz(CO)3Br], respectively. Finally, the ground-state geometrical structures and the UV/Vis absorption spectra in CH2Cl2 solution were theoretically simulated for [Cu(Ph6PyMz)(DPEphos)]BF4 and [RePh6PyMz(CO)3Br].
- The diimine compound 1-[(2',3',4',5'-tetraphenylbiphenyl-4-yl)methyl]-2-(pyridin-2-yl)-1H-benzo[d]imidazole (Ph6PyMz) has been designed and synthesized in order to prepare [Cu(Ph6PyMz)(DPEphos)]BF4 {DPEphos = bis[2-(diphenylphosphanyl)phenyl] ether} and [RePh6PyMz(CO)3Br]. The molecular structures of [Cu(Ph6PyMz)(DPEphos)]BF4 and [RePh6PyMz(CO)3Br] were determined by single-crystal X-ray diffraction and IR spectroscopy, and their properties were systematically studied by thermal-stability analyses, photophysical analyses, and electrochemistry. It was found that [Cu(Ph6PyMz)(DPEphos)]BF4 and [RePh6PyMz(CO)3Br] mainly give triplet-ligand-to-ligand charge-transfer transition emission in CH2Cl2 solution and pure triplet-metal-to-ligand charge-transfer transition emission in the solid state. The different photophysical behaviors of [Cu(Ph6PyMz)(DPEphos)]BF4 and [RePh6PyMz(CO)3Br] in different states has been attributed to solvent effects and their higher freedom in CH2Cl2 solution. The energy levels of the highest-occupied and lowest-unoccupied molecular orbitals were measured to be 5.76 and 3.11 eV for [Cu(Ph6PyMz)(DPEphos)]BF4 and 5.69 and 3.42 eV for [RePh6PyMz(CO)3Br], respectively. Finally, the ground-state geometrical structures and the UV/Vis absorption spectra in CH2Cl2 solution were theoretically simulated for [Cu(Ph6PyMz)(DPEphos)]BF4 and [RePh6PyMz(CO)3Br]. (en)
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| Title
| - 2,3,4,5-Tetraphenylbiphenyl-Containing CuI/ReI Complexes: Synthesis, Property Analysis and Theoretical Studies
- 2,3,4,5-Tetraphenylbiphenyl-Containing CuI/ReI Complexes: Synthesis, Property Analysis and Theoretical Studies (en)
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| skos:prefLabel
| - 2,3,4,5-Tetraphenylbiphenyl-Containing CuI/ReI Complexes: Synthesis, Property Analysis and Theoretical Studies
- 2,3,4,5-Tetraphenylbiphenyl-Containing CuI/ReI Complexes: Synthesis, Property Analysis and Theoretical Studies (en)
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| skos:notation
| - RIV/61388963:_____/12:00385618!RIV13-AV0-61388963
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
| |
| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388963:_____/12:00385618
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| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - copper; rhenium; materials science; photophysics; synthesis design (en)
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| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| - European Journal of Inorganic Chemistry
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...iv/tvurceVysledku
| - Sun, H.
- Sun, X.
- Duan, Q.
- Si, Zhenjun
- Wan, Y.
- Xiang, Q.
- Zhu, G.
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| http://linked.open...ain/vavai/riv/wos
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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| http://bibframe.org/vocab/doi
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