About: Radical Chemistry in the Gas Phase

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	We discuss the role of isolated radicals in various chemical environments, like combustion engines, low-temperature plasmas, planetary atmospheres and interstellar space. Several methods to generate radicals are presented, e.g. pyrolysis, photolysis, discharges, chemical reactions and neutralization-reionization mass spectrometry. The breadth of each method is illustrated and species generated by these methods are introduced. It is shown that photoionization is an important tool to detect radicals and unravel their reactions. However, the often small Franck-Condon-factors have to be considered when interpreting photoionization data. Selected results on the unimolecular and bimolecular reactions of radicals are discussed with the intention to show the scope of present methods to study radical chemistry in the gas phase. Among these methods are time-resolved laser spectroscopy, mass spectrometric techniques like charge-tagging and schemes based on detecting radicals with synchrotron radiation. We discuss the role of isolated radicals in various chemical environments, like combustion engines, low-temperature plasmas, planetary atmospheres and interstellar space. Several methods to generate radicals are presented, e.g. pyrolysis, photolysis, discharges, chemical reactions and neutralization-reionization mass spectrometry. The breadth of each method is illustrated and species generated by these methods are introduced. It is shown that photoionization is an important tool to detect radicals and unravel their reactions. However, the often small Franck-Condon-factors have to be considered when interpreting photoionization data. Selected results on the unimolecular and bimolecular reactions of radicals are discussed with the intention to show the scope of present methods to study radical chemistry in the gas phase. Among these methods are time-resolved laser spectroscopy, mass spectrometric techniques like charge-tagging and schemes based on detecting radicals with synchrotron radiation. (en)
Title	Radical Chemistry in the Gas Phase Radical Chemistry in the Gas Phase (en)
skos:prefLabel	Radical Chemistry in the Gas Phase Radical Chemistry in the Gas Phase (en)
skos:notation	RIV/61388963:_____/12:00379760!RIV13-AV0-61388963
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z40550506)
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Schröder, Detlef
http://linked.open.../riv/druhVysledku	C - Kapitola v knize
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	163928
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/12:00379760
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	radicals; reactive intermediates; gas phase; photoionization; unimolecular reactions; bimolecular reactions (en)
http://linked.open.../riv/klicoveSlovo	gas phase bimolecular reactions reactive intermediates unimolecular reactions photoionization radicals
http://linked.open...ontrolniKodProRIV	[E4FD87CDB0A5]
http://linked.open...i/riv/mistoVydani	New York
http://linked.open...i/riv/nazevZdroje	Encyclopedia of Radicals in Chemistry, Biology and Materials
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...v/pocetStranKnihy	2324 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...UplatneniVysledku	2012
http://linked.open...iv/tvurceVysledku	Schröder, Detlef Alcaraz, Ch. Fischer, I.
http://linked.open...n/vavai/riv/zamer	Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství
number of pages	26 (xsd:int)
http://purl.org/ne...btex#hasPublisher	John Wiley and Sons
https://schema.org/isbn	978-0-470-97125-3

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