About: Formation of Tebuconazole Complexes with Cadmium(II) Investigated by Electrospray Ionization Mass Spectrometry

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The formation of complexes between tebuconazole (Teb) and cadmium in simplified model solutions as well as soil solutions was studied using electrospray ionization mass spectrometry. Teb and cadmium form two types of complexes with the general formulas [Cd(Teb) (n) ](2+) (n = 1-4) and [CdI(Teb) (m) ](+) (m = 1-3), where iodine corresponds to the counterion used. The most intense Teb/cadmium complex is [CdI(Teb)(2)](+), and the most stable one is [Cd(Teb)(Teb - H)](+). Another detected complex, the dication [Cd(Teb)(4)](2+), was considered as the origin complex for the iodine-free complexes and was found in a sample prepared from forest soil solution naturally contaminated with cadmium ions. The formation of complexes between tebuconazole (Teb) and cadmium in simplified model solutions as well as soil solutions was studied using electrospray ionization mass spectrometry. Teb and cadmium form two types of complexes with the general formulas [Cd(Teb) (n) ](2+) (n = 1-4) and [CdI(Teb) (m) ](+) (m = 1-3), where iodine corresponds to the counterion used. The most intense Teb/cadmium complex is [CdI(Teb)(2)](+), and the most stable one is [Cd(Teb)(Teb - H)](+). Another detected complex, the dication [Cd(Teb)(4)](2+), was considered as the origin complex for the iodine-free complexes and was found in a sample prepared from forest soil solution naturally contaminated with cadmium ions. (en)
Title	Formation of Tebuconazole Complexes with Cadmium(II) Investigated by Electrospray Ionization Mass Spectrometry Formation of Tebuconazole Complexes with Cadmium(II) Investigated by Electrospray Ionization Mass Spectrometry (en)
skos:prefLabel	Formation of Tebuconazole Complexes with Cadmium(II) Investigated by Electrospray Ionization Mass Spectrometry Formation of Tebuconazole Complexes with Cadmium(II) Investigated by Electrospray Ionization Mass Spectrometry (en)
skos:notation	RIV/61388963:_____/12:00379216!RIV13-AV0-61388963
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z40550506), Z(MSM6046070901)
http://linked.open...iv/cisloPeriodika	5
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Jaklová Dytrtová, Jana Norková, Renáta Schröder, Detlef
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	137002
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/12:00379216
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ESI-MS; hazardous metals; stoichiometry; triazole fungicides (en)
http://linked.open.../riv/klicoveSlovo	stoichiometry hazardous metals ESI-MS triazole fungicides
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[73FCF34EE576]
http://linked.open...i/riv/nazevZdroje	Water, Air and Soil Pollution
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	223
http://linked.open...iv/tvurceVysledku	Jakl, M. Jaklová Dytrtová, Jana Schröder, Detlef Norková, Renáta
http://linked.open...ain/vavai/riv/wos	000304467000058
http://linked.open...n/vavai/riv/zamer	Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství Setrvalé zemědělství, kvalita zemědělské produkce, krajinné a přírodní zdroje.
issn	0049-6979
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s11270-011-1055-7

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