About: Transition-Metal-Mediated or -Catalyzed Syntheses of Steroids and Steroid-Like Compounds     Goto   Sponge   NotDistinct   Permalink

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  • This short review aims to summarize recent advances in the use of transition-metal-catalyzed and -mediated methodology for the synthesis of steroid and steroid-like skeletons reported in the last decade. The methodologies used include transition-metal-catalyzed or -mediated [2+2+2] and other cycloadditions, the Pauson-Khand reaction, cross-coupling and Heck reactions, processes based on the activation of single and multiple bonds, metathesis reactions, hydrovinylation, and other reactions. Several examples of total syntheses of steroid compounds [e.g., (+)- and (-)-estrone, desogestrel] by these procedures are presented.
  • This short review aims to summarize recent advances in the use of transition-metal-catalyzed and -mediated methodology for the synthesis of steroid and steroid-like skeletons reported in the last decade. The methodologies used include transition-metal-catalyzed or -mediated [2+2+2] and other cycloadditions, the Pauson-Khand reaction, cross-coupling and Heck reactions, processes based on the activation of single and multiple bonds, metathesis reactions, hydrovinylation, and other reactions. Several examples of total syntheses of steroid compounds [e.g., (+)- and (-)-estrone, desogestrel] by these procedures are presented. (en)
Title
  • Transition-Metal-Mediated or -Catalyzed Syntheses of Steroids and Steroid-Like Compounds
  • Transition-Metal-Mediated or -Catalyzed Syntheses of Steroids and Steroid-Like Compounds (en)
skos:prefLabel
  • Transition-Metal-Mediated or -Catalyzed Syntheses of Steroids and Steroid-Like Compounds
  • Transition-Metal-Mediated or -Catalyzed Syntheses of Steroids and Steroid-Like Compounds (en)
skos:notation
  • RIV/61388963:_____/12:00377443!RIV13-AV0-61388963
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  • I, P(1M0508), Z(AV0Z40550506), Z(MSM0021620857)
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  • 1
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  • 174925
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  • RIV/61388963:_____/12:00377443
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  • steroids; synthesis design; synthetic methods; asymmetric synthesis; transition metals (en)
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  • DE - Spolková republika Německo
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  • [C8BEAAA08AC5]
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  • European Journal of Organic Chemistry
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  • Kotora, Martin
  • Hessler, F.
  • Eignerová, B.
http://linked.open...ain/vavai/riv/wos
  • 000299294000003
http://linked.open...n/vavai/riv/zamer
issn
  • 1434-193X
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/ejoc.201100921
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