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  • Tetramethylcyclobutadiene–AlCl3 complex reacted with bisalkynes possessing phenylene and biphenylene spacer giving rise to mono- and bis-Dewar benzenes. The rearrangement of the bis-Dewar benzene derivatives under thermal conditions (150 °C) yielded the corresponding linear ter- and quaterphenyl compounds possessing substituted terminal benzene rings. A mixture of an alkynylbiphenyl and a terphenyl was also obtained by the reaction of tetramethylzirconacyclopentadiene with bisalkynylbenzene in 13% combined yield.
  • Tetramethylcyclobutadiene–AlCl3 complex reacted with bisalkynes possessing phenylene and biphenylene spacer giving rise to mono- and bis-Dewar benzenes. The rearrangement of the bis-Dewar benzene derivatives under thermal conditions (150 °C) yielded the corresponding linear ter- and quaterphenyl compounds possessing substituted terminal benzene rings. A mixture of an alkynylbiphenyl and a terphenyl was also obtained by the reaction of tetramethylzirconacyclopentadiene with bisalkynylbenzene in 13% combined yield. (en)
Title
  • Synthesis of Substituted Linear Ter- and Quaterphenyls via Dewar Benzenes
  • Synthesis of Substituted Linear Ter- and Quaterphenyls via Dewar Benzenes (en)
skos:prefLabel
  • Synthesis of Substituted Linear Ter- and Quaterphenyls via Dewar Benzenes
  • Synthesis of Substituted Linear Ter- and Quaterphenyls via Dewar Benzenes (en)
skos:notation
  • RIV/61388963:_____/11:00369763!RIV12-AV0-61388963
http://linked.open...avai/riv/aktivita
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  • P(IAA401110805), P(LC06070), Z(AV0Z40550506), Z(MSM0021620857)
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  • 3
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  • 233919
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  • RIV/61388963:_____/11:00369763
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  • dewar benzene; alkynes; cyclobutadiene; polycycles; metallacycles (en)
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  • DE - Spolková republika Německo
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  • [09FC58708D40]
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  • Synlett
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  • -
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  • Kotora, Martin
  • Hybelbauerová, S.
  • Janková, Š.
http://linked.open...ain/vavai/riv/wos
  • 000286922800023
http://linked.open...n/vavai/riv/zamer
issn
  • 0936-5214
number of pages
http://bibframe.org/vocab/doi
  • 10.1055/s-0030-1259321
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