About: [6]Saddlequat: a [6]helquat captured on its racemization pathway

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About: [6]Saddlequat: a [6]helquat captured on its racemization pathway Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A dicationic [6]helicene congener captured on the racemization pathway in its saddle-shaped geometry is introduced. The dynamic aspects established by experiment and supported by detailed DFT-D calculations are presented visually in the form of a movie (electronic table-of-contents and electronic supplementary information). The title [6]saddlequat was found to be an isolable chiral species on the entirely chiral enantiomerization pathway of a [6]helquat that is discussed as an example of Mislow’s rubber glove’’ molecule. A dicationic [6]helicene congener captured on the racemization pathway in its saddle-shaped geometry is introduced. The dynamic aspects established by experiment and supported by detailed DFT-D calculations are presented visually in the form of a movie (electronic table-of-contents and electronic supplementary information). The title [6]saddlequat was found to be an isolable chiral species on the entirely chiral enantiomerization pathway of a [6]helquat that is discussed as an example of Mislow’s rubber glove’’ molecule. (en)
Title	[6]Saddlequat: a [6]helquat captured on its racemization pathway [6]Saddlequat: a [6]helquat captured on its racemization pathway (en)
skos:prefLabel	[6]Saddlequat: a [6]helquat captured on its racemization pathway [6]Saddlequat: a [6]helquat captured on its racemization pathway (en)
skos:notation	RIV/61388963:_____/11:00363302!RIV12-AV0-61388963
http://linked.open...avai/riv/aktivita	P S Z
http://linked.open...avai/riv/aktivity	P(GA203/08/1428), P(GA203/09/1614), P(GAP207/10/2391), P(GP203/09/P485), S, Z(AV0Z40550506), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	12
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Pohl, Radek Vávra, Jan Severa, Lukáš Koval, Dušan Teplý, Filip Kašička, Václav Šaman, David Sázelová, Petra Adriaenssens, Louis
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	244241
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/11:00363302
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	dynamic stereochemistry; kinetic [2+2+2] cycloaddition; DFT and spectroscopy (en)
http://linked.open.../riv/klicoveSlovo	DFT and spectroscopy dynamic stereochemistry kinetic [2+2+2] cycloaddition
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[5F7B733B74E7]
http://linked.open...i/riv/nazevZdroje	Chemical Science
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	9 (xsd:int)
http://linked.open...cetTvurcuVysledku	14 (xsd:int)
http://linked.open...vavai/riv/projekt	Capillary electrophoresis with multidimensinal detection and its application to separation and characterization of biopolymers Two-dimensional separation techniques for microscale bioanalysis Synthesis of N-Heteroaromatic Cations via Transition Metal Catalysis Synthesis of Helquats and their Organocatalytic Applications
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	2
http://linked.open...iv/tvurceVysledku	Adriaenssens, Louis Císařová, I. Kašička, Václav Koval, Dušan Novotná, P. Pohl, Radek Severa, Lukáš Teplý, Filip Vávra, Jan Šaman, David Urbanová, M. Belmonte, M. M. Escudero-Adán, E. C. Sázelová, Petra
http://linked.open...ain/vavai/riv/wos	000296745500005
http://linked.open...n/vavai/riv/zamer	Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	2041-6520
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1039/c1sc00468a

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