About: Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen     Goto   Sponge   NotDistinct   Permalink

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Description
  • Para- and meta-nitro-(pentafluorosulfanyl)benzenes react with anions of cumyl hydroperoxide in the presence of t-BuOK in liquid ammonia to form nitro-(pentafluorosulfanyl)phenols. Their reduction with hydrogen in the presence of Raney-Nickel provides amino-(pentafluorosulfanyl)phenols.
  • Para- and meta-nitro-(pentafluorosulfanyl)benzenes react with anions of cumyl hydroperoxide in the presence of t-BuOK in liquid ammonia to form nitro-(pentafluorosulfanyl)phenols. Their reduction with hydrogen in the presence of Raney-Nickel provides amino-(pentafluorosulfanyl)phenols. (en)
Title
  • Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen
  • Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen (en)
skos:prefLabel
  • Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen
  • Hydroxylation of nitro-(pentafluorosulfanyl)benzenes via vicarious nucleophilic substitution of hydrogen (en)
skos:notation
  • RIV/61388963:_____/11:00361469!RIV12-AV0-61388963
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  • P(GAP207/11/0344), Z(AV0Z40550506)
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  • 34
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  • 203180
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  • RIV/61388963:_____/11:00361469
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  • pentafluorosulfanyl group; vicarious nucleophilic substitution; hydroxylation (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [C1249472AA47]
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  • Tetrahedron Letters
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  • 52
http://linked.open...iv/tvurceVysledku
  • Beier, Petr
  • Pastýříková, Tereza
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  • 000293987000007
http://linked.open...n/vavai/riv/zamer
issn
  • 0040-4039
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.tetlet.2011.06.011
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