About: The study of cadmium - oxalic acid complexes using DPASV and ESI-MS     Goto   Sponge   NotDistinct   Permalink

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  • The combination of DPASV with ESI-MS allows a reliable detection of metal complexes with small organic ligands. The request to exact molecular mass is essential to stoichiometry design simultaneously with low concentration of the analyte in most of biological matrixes. By the analysis of model solution consisting of Cd(NO3)(2) and oxalic acid (OAH(2)) these structures were identified: [Cd(OAH(2))(H2O)(2)](+), [Cd(OAH(2))(H2O)(3)](+), and [Cd(OAH(2))(H2O)(2)(CH3OH)](+). They were also found in soil solution. (en)
  • The combination of DPASV with ESI-MS allows a reliable detection of metal complexes with small organic ligands. The request to exact molecular mass is essential to stoichiometry design simultaneously with low concentration of the analyte in most of biological matrixes. By the analysis of model solution consisting of Cd(NO3)(2) and oxalic acid (OAH(2)) these structures were identified: [Cd(OAH(2))(H2O)(2)](+), [Cd(OAH(2))(H2O)(3)](+), and [Cd(OAH(2))(H2O)(2)(CH3OH)](+). They were also found in soil solution.
Title
  • The study of cadmium - oxalic acid complexes using DPASV and ESI-MS
  • The study of cadmium - oxalic acid complexes using DPASV and ESI-MS (en)
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  • The study of cadmium - oxalic acid complexes using DPASV and ESI-MS
  • The study of cadmium - oxalic acid complexes using DPASV and ESI-MS (en)
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  • RIV/61388963:_____/10:00352893!RIV11-AV0-61388963
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  • Z(AV0Z40550506)
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  • 290743
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  • RIV/61388963:_____/10:00352893
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  • electrospray ionization mass spectrometry; differential pulse anodic stripping voltammetry; low-molecular-weight organic acids; metals (en)
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  • [1AE81C304646]
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  • Jetřichovice
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  • 30th Modern Electrochemical Methods
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  • Jakl, M.
  • Jaklová Dytrtová, Jana
  • Tlustoš, P.
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  • 000283050900019
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  • BEST Servis
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  • 978-80-254-6710-7
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