About: Air-tolerant C–C bond formation via organometallic ruthenium catalysis: diverse catalytic pathways involving (C5Me5)Ru or (C5H5)Ru are robust to molecular oxygen

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About: Air-tolerant C–C bond formation via organometallic ruthenium catalysis: diverse catalytic pathways involving (C5Me5)Ru or (C5H5)Ru are robust to molecular oxygen Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Ruthenium-catalyzed substitutions of carbon pronucleophiles, various [2+2+2] cycloadditions, and addition of a diazo compound to an alkyne are shown to proceed in the presence of air. Notably diverse catalytic manifolds remain supported under conditions generally regarded as prohibitive. Building on rare reports from the literature we show that a range of organometallic transformations based on reaction intermediates derived from (C5Me5)Ru or (C5H5)Ru moieties are air-compatible. Ruthenium-catalyzed substitutions of carbon pronucleophiles, various [2+2+2] cycloadditions, and addition of a diazo compound to an alkyne are shown to proceed in the presence of air. Notably diverse catalytic manifolds remain supported under conditions generally regarded as prohibitive. Building on rare reports from the literature we show that a range of organometallic transformations based on reaction intermediates derived from (C5Me5)Ru or (C5H5)Ru moieties are air-compatible. (en)
Title	Air-tolerant C–C bond formation via organometallic ruthenium catalysis: diverse catalytic pathways involving (C5Me5)Ru or (C5H5)Ru are robust to molecular oxygen Air-tolerant C–C bond formation via organometallic ruthenium catalysis: diverse catalytic pathways involving (C5Me5)Ru or (C5H5)Ru are robust to molecular oxygen (en)
skos:prefLabel	Air-tolerant C–C bond formation via organometallic ruthenium catalysis: diverse catalytic pathways involving (C5Me5)Ru or (C5H5)Ru are robust to molecular oxygen Air-tolerant C–C bond formation via organometallic ruthenium catalysis: diverse catalytic pathways involving (C5Me5)Ru or (C5H5)Ru are robust to molecular oxygen (en)
skos:notation	RIV/61388963:_____/09:00330560!RIV10-AV0-61388963
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(AV0Z40550506)
http://linked.open...iv/cisloPeriodika	31
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Kohoutová, Anna Čížková, Martina Šálová, Tereza Hývl, Jakub Pohl, Radek Vávra, Jan Severa, Lukáš Teplý, Filip Šaman, David Adriaenssens, Louis
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	302218
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/09:00330560
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ruthenium; organometallic catalysis; [2+2+2] cycloaddition; terminal alkynes (en)
http://linked.open.../riv/klicoveSlovo	terminal alkynes organometallic catalysis ruthenium [2+2+2] cycloaddition
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[E2C667A0A0E1]
http://linked.open...i/riv/nazevZdroje	Tetrahedron Letters
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	10 (xsd:int)
http://linked.open...cetTvurcuVysledku	10 (xsd:int)
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	50
http://linked.open...iv/tvurceVysledku	Adriaenssens, Louis Pohl, Radek Severa, Lukáš Teplý, Filip Vávra, Jan Šaman, David Čížková, Martina Hývl, Jakub Kohoutová, Anna Šálová, Tereza
http://linked.open...ain/vavai/riv/wos	000267672700034
http://linked.open...n/vavai/riv/zamer	Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství
issn	0040-4039
number of pages	3 (xsd:int)

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