About: Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins

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About: Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A tetrapodal pentadentate nitrogen ligand (2,6-bis(1,1-di(aminomethyl)ethyl)pyridine, 1) is used for the synthesis of the azido-iron(III) complex [(1)Fe(N3)]X2 (X =Br or PF6). Electrospray ionization affords the dication [(1)Fe(N3)]2+ as well as the dicationic nitrido-iron species [(1)FeN]2+. A tetrapodal pentadentate nitrogen ligand (2,6-bis(1,1-di(aminomethyl)ethyl)pyridine, 1) is used for the synthesis of the azido-iron(III) complex [(1)Fe(N3)]X2 (X =Br or PF6). Electrospray ionization affords the dication [(1)Fe(N3)]2+ as well as the dicationic nitrido-iron species [(1)FeN]2+. (en) Tetrapodální pentadentální dusíkatý ligand (2,6-bis(1,1-di(aminomethyl)ethyl)pyridine, 1) je používán pro syntézu komplexu azidu kovu(III) [(1)Fe(N3)]X2 (X =Br or PF6). Electrospray ionizace poskytuje dikationt [(1)Fe(N3)]2+ spolu s dikationickými sloučeninami nitridů kovu [(1)FeN]2+. (cs)
Title	Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins (en) Aktivace C-H a N-H vazeb v plynné fázi vysoce valentním dikationtem nitridu kovu a {NH}-přenos k aktivaci olefinů (cs)
skos:prefLabel	Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins Gas-phase C-H and N-H bond activation by a high valent nitrido-iron dication and {NH}-transfer to activated olefins (en) Aktivace C-H a N-H vazeb v plynné fázi vysoce valentním dikationtem nitridu kovu a {NH}-přenos k aktivaci olefinů (cs)
skos:notation	RIV/61388963:_____/08:00314403!RIV09-AV0-61388963
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(KJB400550704), Z(AV0Z40550506)
http://linked.open...iv/cisloPeriodika	13
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Schröder, Detlef
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav organické chemie a biochemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	368957
http://linked.open...ai/riv/idVysledku	RIV/61388963:_____/08:00314403
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	azides; bond activation; dications; iron; mass spectrometry; metal nitrenes (en)
http://linked.open.../riv/klicoveSlovo	azides mass spectrometry bond activation iron dications metal nitrenes
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[A8C481A903F5]
http://linked.open...i/riv/nazevZdroje	Journal of the American Chemical Society
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	9 (xsd:int)
http://linked.open...vavai/riv/projekt	Intrinsic properties of redox-active molecules
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	130
http://linked.open...iv/tvurceVysledku	Neugebauer, J. Schröder, Detlef Schwarz, H. Schlangen, M. Reiher, M. Grohmann, A. Haryono, M. Heinemann, F. W. López, J. P.
http://linked.open...ain/vavai/riv/wos	000254549000028
http://linked.open...n/vavai/riv/zamer	Regulace biologických procesů: Chemické modulátory vybraných systémů významných pro medicínu a zemědělství
issn	0002-7863
number of pages	10 (xsd:int)

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