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Description
  • We demonstrate the strong influence of a solvent on the tautomeric equilibrium between the tautomers of bases and on the spatial arrangement of the bases in a base pair. The results provide clear evidence that the prevalence of either the stacked or hydrogen-bonded structures of the base pairs in the solvent is not determined only by its bulk properties, but rather by specific hydrophilic interactions of the base pair with a small number of solvent molecules.
  • We demonstrate the strong influence of a solvent on the tautomeric equilibrium between the tautomers of bases and on the spatial arrangement of the bases in a base pair. The results provide clear evidence that the prevalence of either the stacked or hydrogen-bonded structures of the base pairs in the solvent is not determined only by its bulk properties, but rather by specific hydrophilic interactions of the base pair with a small number of solvent molecules. (en)
  • V článku je ukázán vliv hydratace na tautomerní rovnováhu bází nukleových kyselin a prostorové uspořádání párů bází. Je ukázán význam specifických interakcí bází s molekulami rozpouštědla. (cs)
Title
  • Hydration and stability of nucleic acid bases and base pairs
  • Hydratace a stabilita bází nukleových kyselin a jejich párů (cs)
  • Hydration and stability of nucleic acid bases and base pairs (en)
skos:prefLabel
  • Hydration and stability of nucleic acid bases and base pairs
  • Hydratace a stabilita bází nukleových kyselin a jejich párů (cs)
  • Hydration and stability of nucleic acid bases and base pairs (en)
skos:notation
  • RIV/61388963:_____/07:00090323!RIV08-AV0-61388963
http://linked.open.../vavai/riv/strany
  • 903;917
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/05/0009), P(KJB400550518), P(LC512), Z(AV0Z40550506)
http://linked.open...iv/cisloPeriodika
  • 8
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 425058
http://linked.open...ai/riv/idVysledku
  • RIV/61388963:_____/07:00090323
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • hydratation; nucleic acid base; base pairs; stacking; H-bonding (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [E3B41647EE28]
http://linked.open...i/riv/nazevZdroje
  • Physical Chemistry Chemical Physics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 9
http://linked.open...iv/tvurceVysledku
  • Hobza, Pavel
  • Kabeláč, Martin
http://linked.open...n/vavai/riv/zamer
issn
  • 1463-9076
number of pages
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