About: Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations

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About: Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Four new compounds composed of chiral complex cations and anions: Δ-[Fe(bpy)3] Λ-[Fe(bpy)3][V4O8((2R,3R)-tart)2]12H2O (1), Δ-[Fe(bpy)3]2Λ-[Fe(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (2), Δ-[Ni(bpy)3]Λ-[Ni(bpy)3][V4O8((2R,3R)-tart)2]12H2O (3) and Δ-[Ni(bpy)3]2Λ-[Ni(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (4) have been prepared. The compounds have been characterized by spectral methods, and their thermal decomposition was studied by simultaneous DTA, TG measurements. The final products after dynamic decomposition and additional heating were Fe2V4O13 for 1 and 2 and Ni(VO3)2 for 3 and 4. The crystal structures determined for 1, 2 and 4 have evidenced that 1 is %22hemiracemic%22 and 2 and 4 are %22fully racemic%22 compounds. Four new compounds composed of chiral complex cations and anions: Δ-[Fe(bpy)3] Λ-[Fe(bpy)3][V4O8((2R,3R)-tart)2]12H2O (1), Δ-[Fe(bpy)3]2Λ-[Fe(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (2), Δ-[Ni(bpy)3]Λ-[Ni(bpy)3][V4O8((2R,3R)-tart)2]12H2O (3) and Δ-[Ni(bpy)3]2Λ-[Ni(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (4) have been prepared. The compounds have been characterized by spectral methods, and their thermal decomposition was studied by simultaneous DTA, TG measurements. The final products after dynamic decomposition and additional heating were Fe2V4O13 for 1 and 2 and Ni(VO3)2 for 3 and 4. The crystal structures determined for 1, 2 and 4 have evidenced that 1 is %22hemiracemic%22 and 2 and 4 are %22fully racemic%22 compounds. (en)
Title	Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations (en)
skos:prefLabel	Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations (en)
skos:notation	RIV/61388955:_____/14:00434756!RIV15-AV0-61388955
http://linked.open...avai/riv/aktivita	I
http://linked.open...avai/riv/aktivity	I
http://linked.open...iv/cisloPeriodika	8
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Gyepes, Robert
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	22269
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/14:00434756
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	RACEMIC COMPOUND FORMATION; TRIS(DIIMINE)-METAL COMPLEXES; CONGLOMERATE FORMATION (en)
http://linked.open.../riv/klicoveSlovo	CONGLOMERATE FORMATION RACEMIC COMPOUND FORMATION TRIS(DIIMINE)-METAL COMPLEXES
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[955923C068D1]
http://linked.open...i/riv/nazevZdroje	Transition Metal Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	39
http://linked.open...iv/tvurceVysledku	Gyepes, Robert Tatiersky, J. Antal, P. Schwendt, P. Drábik, M.
http://linked.open...ain/vavai/riv/wos	000343836900007
issn	0340-4285
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s11243-014-9873-2

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