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rdf:type
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Description
| - Four new compounds composed of chiral complex cations and anions: Δ-[Fe(bpy)3] Λ-[Fe(bpy)3][V4O8((2R,3R)-tart)2]12H2O (1), Δ-[Fe(bpy)3]2Λ-[Fe(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (2), Δ-[Ni(bpy)3]Λ-[Ni(bpy)3][V4O8((2R,3R)-tart)2]12H2O (3) and Δ-[Ni(bpy)3]2Λ-[Ni(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (4) have been prepared. The compounds have been characterized by spectral methods, and their thermal decomposition was studied by simultaneous DTA, TG measurements. The final products after dynamic decomposition and additional heating were Fe2V4O13 for 1 and 2 and Ni(VO3)2 for 3 and 4. The crystal structures determined for 1, 2 and 4 have evidenced that 1 is %22hemiracemic%22 and 2 and 4 are %22fully racemic%22 compounds.
- Four new compounds composed of chiral complex cations and anions: Δ-[Fe(bpy)3] Λ-[Fe(bpy)3][V4O8((2R,3R)-tart)2]12H2O (1), Δ-[Fe(bpy)3]2Λ-[Fe(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (2), Δ-[Ni(bpy)3]Λ-[Ni(bpy)3][V4O8((2R,3R)-tart)2]12H2O (3) and Δ-[Ni(bpy)3]2Λ-[Ni(bpy)3]2[V4O8((2R,3R)-tart)2][V4O8((2S,3S)-tart)2]24H2O (4) have been prepared. The compounds have been characterized by spectral methods, and their thermal decomposition was studied by simultaneous DTA, TG measurements. The final products after dynamic decomposition and additional heating were Fe2V4O13 for 1 and 2 and Ni(VO3)2 for 3 and 4. The crystal structures determined for 1, 2 and 4 have evidenced that 1 is %22hemiracemic%22 and 2 and 4 are %22fully racemic%22 compounds. (en)
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Title
| - Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations
- Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations (en)
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skos:prefLabel
| - Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations
- Interaction between chiral ions: synthesis and characterization of tartratovanadates(V) with tris(2,2-bipyridine) complexes of iron(II) and nickel(II) as cations (en)
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skos:notation
| - RIV/61388955:_____/14:00434756!RIV15-AV0-61388955
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/14:00434756
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - RACEMIC COMPOUND FORMATION; TRIS(DIIMINE)-METAL COMPLEXES; CONGLOMERATE FORMATION (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Transition Metal Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Gyepes, Robert
- Tatiersky, J.
- Antal, P.
- Schwendt, P.
- Drábik, M.
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1007/s11243-014-9873-2
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