About: Ion transfer kinetics at the micro-interface between two immiscible electrolyte solutions investigated by electrochemical impedance spectroscopy and steady-state voltammetry

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About: Ion transfer kinetics at the micro-interface between two immiscible electrolyte solutions investigated by electrochemical impedance spectroscopy and steady-state voltammetry Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The kinetics of tetraethylammonium (TEA+) ion transfer across the water/1,2-dichloroethane interface was studied using electrochemical impedance spectroscopy and steady-state voltammetry. The liquid/liquid interface was supported at the tip of a microcapillary. A novel capillary design methodology has advantageously allowed the use of the same microcapillary in a number of different experiments. It is herein shown that the geometry of the microcapillary tip region is of critical importance in order to obtain reliable kinetic data. Both steady-state voltammetry and electrochemical impedance spectroscopy yielded approximately the same apparent standard rate constant of 0.2 cm s1 for TEA+ transfer across the water/1,2-dichloroethane. The kinetics of tetraethylammonium (TEA+) ion transfer across the water/1,2-dichloroethane interface was studied using electrochemical impedance spectroscopy and steady-state voltammetry. The liquid/liquid interface was supported at the tip of a microcapillary. A novel capillary design methodology has advantageously allowed the use of the same microcapillary in a number of different experiments. It is herein shown that the geometry of the microcapillary tip region is of critical importance in order to obtain reliable kinetic data. Both steady-state voltammetry and electrochemical impedance spectroscopy yielded approximately the same apparent standard rate constant of 0.2 cm s1 for TEA+ transfer across the water/1,2-dichloroethane. (en)
Title	Ion transfer kinetics at the micro-interface between two immiscible electrolyte solutions investigated by electrochemical impedance spectroscopy and steady-state voltammetry Ion transfer kinetics at the micro-interface between two immiscible electrolyte solutions investigated by electrochemical impedance spectroscopy and steady-state voltammetry (en)
skos:prefLabel	Ion transfer kinetics at the micro-interface between two immiscible electrolyte solutions investigated by electrochemical impedance spectroscopy and steady-state voltammetry Ion transfer kinetics at the micro-interface between two immiscible electrolyte solutions investigated by electrochemical impedance spectroscopy and steady-state voltammetry (en)
skos:notation	RIV/61388955:_____/14:00431370!RIV15-GA0-61388955
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(GA13-04630S)
http://linked.open...iv/cisloPeriodika	OCT 2014
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Mareček, Vladimír Holub, Karel Silver, Barry Richard
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	22822
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/14:00431370
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Liquid/liquid interfaces; Ion transport; AC impedance (en)
http://linked.open.../riv/klicoveSlovo	Ion transport AC impedance Liquid/liquid interfaces
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[B93EB138FA15]
http://linked.open...i/riv/nazevZdroje	Journal of Electroanalytical Chemistry
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Novel Methodology for the Determination of the Rate of Ion-Transfer Across Liquid/Liquid Interfaces (ITIES)
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	731
http://linked.open...iv/tvurceVysledku	Silver, Barry Richard Mareček, Vladimír Holub, Karel
http://linked.open...ain/vavai/riv/wos	000343633700017
issn	1572-6657
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.jelechem.2014.08.017

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