About: Nanofibrous TiO2 improving performance of mesoporous TiO2 electrode in dye-sensitized solar cell     Goto   Sponge   NotDistinct   Permalink

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  • A method of direct coating of conducting glass by electrospinning was developed. Electrospun fibrous TiO2 consisting of closely packed anatase nanocrystals of 40–50 nm in size was incorporated into mesoporous TiO2 thin film stabilized by phosphorus. The mesoporous framework formed by walls with 5–6 nm TiO2 nanocrystals surrounding 20 nm mesopores exhibits extreme porosity and consequently limited number of necking points. TiO2 with fibrous morphology was found to solidify mesoporous titania and to be beneficial for the performance of corresponding photoanode in dye-sensitized solar cell (DSC). Obviously, its wire-like structure suitably interconnects mesoporous network and thus increases the electron collection efficiency from the TiO2 layer to the F-doped SnO2 electrode. The solar conversion efficiency of a DSC employing optimized photoanode consisting of nanocrystalline fibrous bottom layer, four mesoporous layers, and one nanocrystalline anatase scattering top layer sensitized with the N945 dye reached 5.35 %. This represents an improvement of about 9 % compared to the solar conversion efficiency of a DSC employing purely mesoporous TiO2 layer prepared by means of phosphorus doping (5.05 %).
  • A method of direct coating of conducting glass by electrospinning was developed. Electrospun fibrous TiO2 consisting of closely packed anatase nanocrystals of 40–50 nm in size was incorporated into mesoporous TiO2 thin film stabilized by phosphorus. The mesoporous framework formed by walls with 5–6 nm TiO2 nanocrystals surrounding 20 nm mesopores exhibits extreme porosity and consequently limited number of necking points. TiO2 with fibrous morphology was found to solidify mesoporous titania and to be beneficial for the performance of corresponding photoanode in dye-sensitized solar cell (DSC). Obviously, its wire-like structure suitably interconnects mesoporous network and thus increases the electron collection efficiency from the TiO2 layer to the F-doped SnO2 electrode. The solar conversion efficiency of a DSC employing optimized photoanode consisting of nanocrystalline fibrous bottom layer, four mesoporous layers, and one nanocrystalline anatase scattering top layer sensitized with the N945 dye reached 5.35 %. This represents an improvement of about 9 % compared to the solar conversion efficiency of a DSC employing purely mesoporous TiO2 layer prepared by means of phosphorus doping (5.05 %). (en)
Title
  • Nanofibrous TiO2 improving performance of mesoporous TiO2 electrode in dye-sensitized solar cell
  • Nanofibrous TiO2 improving performance of mesoporous TiO2 electrode in dye-sensitized solar cell (en)
skos:prefLabel
  • Nanofibrous TiO2 improving performance of mesoporous TiO2 electrode in dye-sensitized solar cell
  • Nanofibrous TiO2 improving performance of mesoporous TiO2 electrode in dye-sensitized solar cell (en)
skos:notation
  • RIV/61388955:_____/13:00392402!RIV14-GA0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP108/12/0814)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 90589
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/13:00392402
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • dye-sensitized solar cells; titanium dioxide; nanofibers (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [0358885442FB]
http://linked.open...i/riv/nazevZdroje
  • Journal of Nanoparticle Research
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 15
http://linked.open...iv/tvurceVysledku
  • Kavan, Ladislav
  • Zukalová, Markéta
  • Zukal, Arnošt
  • Procházka, Jan
  • Grätzel, M.
  • Yum, J. H.
http://linked.open...ain/vavai/riv/wos
  • 000318555400045
issn
  • 1388-0764
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s11051-013-1640-3
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