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  • Titania nanofibers were fabricated using the industrial Nanospider(TM) technology. The preparative protocol was optimized by screening various precursor materials to get pure anatase nanofibers. Composite films were prepared by mixing a commercial paste of nanocrystalline anatase particles with the electrospun nanofibers, which were shortened by milling. The composite films were sensitized by Ru-bipyridine dye (coded C106) and the solar conversion efficiency was tested in a dye-sensitized solar cell filled with iodide-based electrolyte solution (coded Z960). The solar conversion efficiency of a solar cell with the optimized composite electrode (η = 7.53% at AM 1.5 irradiation) outperforms that of a solar cell with pure nanoparticle film (η = 5.44%). Still larger improvement was found for lower light intensities. At 10% sun illumination, the best composite electrode showed η = 7.04%, referenced to that of pure nanoparticle film (η = 4.69%). There are non-monotonic relations between the film's surface area, dye sorption capacity and solar performance of nanofiber-containing composite films, but the beneficial effect of the nanofiber morphology for enhancement of the solar efficiency has been demonstrated.
  • Titania nanofibers were fabricated using the industrial Nanospider(TM) technology. The preparative protocol was optimized by screening various precursor materials to get pure anatase nanofibers. Composite films were prepared by mixing a commercial paste of nanocrystalline anatase particles with the electrospun nanofibers, which were shortened by milling. The composite films were sensitized by Ru-bipyridine dye (coded C106) and the solar conversion efficiency was tested in a dye-sensitized solar cell filled with iodide-based electrolyte solution (coded Z960). The solar conversion efficiency of a solar cell with the optimized composite electrode (η = 7.53% at AM 1.5 irradiation) outperforms that of a solar cell with pure nanoparticle film (η = 5.44%). Still larger improvement was found for lower light intensities. At 10% sun illumination, the best composite electrode showed η = 7.04%, referenced to that of pure nanoparticle film (η = 4.69%). There are non-monotonic relations between the film's surface area, dye sorption capacity and solar performance of nanofiber-containing composite films, but the beneficial effect of the nanofiber morphology for enhancement of the solar efficiency has been demonstrated. (en)
Title
  • The Application of Electrospun Titania Nanofibers in Dye-sensitized Solar Cells
  • The Application of Electrospun Titania Nanofibers in Dye-sensitized Solar Cells (en)
skos:prefLabel
  • The Application of Electrospun Titania Nanofibers in Dye-sensitized Solar Cells
  • The Application of Electrospun Titania Nanofibers in Dye-sensitized Solar Cells (en)
skos:notation
  • RIV/61388955:_____/13:00391766!RIV14-GA0-61388955
http://linked.open...avai/riv/aktivita
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  • I, P(GA203/08/0604), P(IAA400400804), P(KAN200100801)
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  • 3
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  • 61718
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  • RIV/61388955:_____/13:00391766
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  • dye-sensitized solar cells; electrospinning; titanium dioxide (en)
http://linked.open.../riv/klicoveSlovo
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  • CH - Švýcarská konfederace
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  • [89F98064C35B]
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  • Chimia
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  • 67
http://linked.open...iv/tvurceVysledku
  • Kavan, Ladislav
  • Zukal, Arnošt
  • Grätzel, M.
  • Nazeeruddin, M. K.
  • Chandiran, A. K.
  • Krýsová, Hana
  • Trčková-Baraková, J.
http://linked.open...ain/vavai/riv/wos
  • 000317024300007
issn
  • 0009-4293
number of pages
http://bibframe.org/vocab/doi
  • 10.2533/chimia.2013.149
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