About: Tubular Detector of Silver Solid Amalgam for Electrochemical Measurements in Flow Systems

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	This paper presents the application of the tubular detector based on silver solid amalgam (TD-AgSA) for electrochemical determinations of reducible inorganic (Cd2+, Zn2+) and organic (4-nitrophenol) compounds under flow injection analysis conditions. The newly developed TD-AgSA is simple, robust and inexpensive. The limits of detections of Zn2+, Cd2+ and 4-nitrophenol are 1.4106, 7.0107, and 5.0107 mol dm3, respectively (i.e. 0.09, 0.08 and 0.07 ppm). The obtained results proved the long-term stability of the detector (RSD of the determination of Zn2+, Cd2+, and 4-nitrophenol were 0.8, 0.9 and 0.8 % (n=10; cZn=7.7105 mol dm3, cCd=4.5105 mol dm3 and c4-NPh=3.6105 mol dm3), respectively and its applicability for cathodic measurements in aqueous solutions at potentials up to 2 V. This paper presents the application of the tubular detector based on silver solid amalgam (TD-AgSA) for electrochemical determinations of reducible inorganic (Cd2+, Zn2+) and organic (4-nitrophenol) compounds under flow injection analysis conditions. The newly developed TD-AgSA is simple, robust and inexpensive. The limits of detections of Zn2+, Cd2+ and 4-nitrophenol are 1.4106, 7.0107, and 5.0107 mol dm3, respectively (i.e. 0.09, 0.08 and 0.07 ppm). The obtained results proved the long-term stability of the detector (RSD of the determination of Zn2+, Cd2+, and 4-nitrophenol were 0.8, 0.9 and 0.8 % (n=10; cZn=7.7105 mol dm3, cCd=4.5105 mol dm3 and c4-NPh=3.6105 mol dm3), respectively and its applicability for cathodic measurements in aqueous solutions at potentials up to 2 V. (en)
Title	Tubular Detector of Silver Solid Amalgam for Electrochemical Measurements in Flow Systems Tubular Detector of Silver Solid Amalgam for Electrochemical Measurements in Flow Systems (en)
skos:prefLabel	Tubular Detector of Silver Solid Amalgam for Electrochemical Measurements in Flow Systems Tubular Detector of Silver Solid Amalgam for Electrochemical Measurements in Flow Systems (en)
skos:notation	RIV/61388955:_____/12:00385013!RIV13-GA0-61388955
http://linked.open...avai/riv/aktivita	I P S
http://linked.open...avai/riv/aktivity	I, P(GAP206/11/1638), S
http://linked.open...iv/cisloPeriodika	12
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Yosypchuk, Bogdan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	175299
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/12:00385013
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	flow injection analysis; tubular detector; silver solid amalgam (en)
http://linked.open.../riv/klicoveSlovo	flow injection analysis silver solid amalgam tubular detector
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[E68F355E7F50]
http://linked.open...i/riv/nazevZdroje	Electroanalysis
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Novel electrochemical sensors and sensing techniques for the analysis of nucleic acids structure and interactions
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	24
http://linked.open...iv/tvurceVysledku	Barek, J. Yosypchuk, Bogdan Yosypchuk, O.
http://linked.open...ain/vavai/riv/wos	000311910800003
issn	1040-0397
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1002/elan.201200443

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