About: Optimization of a Flow Rate for a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry     Goto   Sponge   NotDistinct   Permalink

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  • The hyphenation of an electrochemical cell prior to mass spectrometer with electrospray ionization allows studying of products and/or of intermediates of electrode reactions. The measurement is realized in a flowing system. The flow rate of the sample markedly influences the MS signal intensity of the product. The calculated optimum value for the electrochemical cell with the sweep volume 0.72 μL is in the range from 0.4 to 0.5 mL h -1 . The experimental optimal value is 0.45 mL h -1 . The optimization of the flow rate has to be provided individually for each product, because the intensity also depends on the rate of the electrode reaction and product stability.
  • The hyphenation of an electrochemical cell prior to mass spectrometer with electrospray ionization allows studying of products and/or of intermediates of electrode reactions. The measurement is realized in a flowing system. The flow rate of the sample markedly influences the MS signal intensity of the product. The calculated optimum value for the electrochemical cell with the sweep volume 0.72 μL is in the range from 0.4 to 0.5 mL h -1 . The experimental optimal value is 0.45 mL h -1 . The optimization of the flow rate has to be provided individually for each product, because the intensity also depends on the rate of the electrode reaction and product stability. (en)
Title
  • Optimization of a Flow Rate for a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry
  • Optimization of a Flow Rate for a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry (en)
skos:prefLabel
  • Optimization of a Flow Rate for a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry
  • Optimization of a Flow Rate for a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry (en)
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  • RIV/61388955:_____/12:00384357!RIV13-GA0-61388955
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  • I, P(GAP208/12/1645), P(IAA400400806)
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  • 156931
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  • RIV/61388955:_____/12:00384357
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  • electrochemistry; amperometry; ESI-MS (en)
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  • [98046C00EF83]
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  • Jetřichovice
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  • Ústí nad Labem
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  • XXXII. Moderní elektrochemické metody. Sborník přednášek
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  • Jakl, M.
  • Jaklová Dytrtová, Jana
  • Navrátil, Tomáš
  • Norková, Renáta
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number of pages
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  • BEST servis
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  • 978-80-905221-0-7
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