About: High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Catalytic behavior of metal-organic-frameworks (MOFs) Cu-3(BTC)(2), MIL-100(Fe) and MIL-100(Cr) was investigated in p-xylene acylation with benzoyl chloride and compared with the behavior of large pore zeolites Beta and USY. It has been clearly shown that MIL-100(Fe) exhibit much higher conversion of benzoyl chloride with excellent selectivity in p-xylene acylation. The performance of MIL-100(Fe) catalyst was favorable with those of other conventional heterogeneous catalysts like zeolites. Conversion of benzoyl chloride equal to 100% was achieved over MIL-100(Fe) with 20-30 min under optimized reaction conditions. It is assumed that unsaturated Lewis acid sites associated with the presence of Fe exhibit optimum acid strength for catalyzing this acylation reaction. Catalytic behavior of metal-organic-frameworks (MOFs) Cu-3(BTC)(2), MIL-100(Fe) and MIL-100(Cr) was investigated in p-xylene acylation with benzoyl chloride and compared with the behavior of large pore zeolites Beta and USY. It has been clearly shown that MIL-100(Fe) exhibit much higher conversion of benzoyl chloride with excellent selectivity in p-xylene acylation. The performance of MIL-100(Fe) catalyst was favorable with those of other conventional heterogeneous catalysts like zeolites. Conversion of benzoyl chloride equal to 100% was achieved over MIL-100(Fe) with 20-30 min under optimized reaction conditions. It is assumed that unsaturated Lewis acid sites associated with the presence of Fe exhibit optimum acid strength for catalyzing this acylation reaction. (en)
Title	High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride (en)
skos:prefLabel	High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride High activity of iron containing metal-organic-framework in acylation of p-xylene with benzoyl chloride (en)
skos:notation	RIV/61388955:_____/12:00375913!RIV13-GA0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA104/07/0383), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Čejka, Jiří Kurfiřtová, Lenka
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	138915
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/12:00375913
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	acylation; p-xylene; zeolites (en)
http://linked.open.../riv/klicoveSlovo	acylation p-xylene zeolites
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[5857E1B3F795]
http://linked.open...i/riv/nazevZdroje	Catalysis Today
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Development of new heterogeneous catalysts for acylation reactions
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	179
http://linked.open...iv/tvurceVysledku	Čejka, Jiří Kurfiřtová, Lenka Chang, J. - S. Hwang, Y. K. Seo, Y. - K.
http://linked.open...ain/vavai/riv/wos	000298404600011
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0920-5861
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.cattod.2011.08.001

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 48 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software