About: Vinyl-ruthenium entities as markers for intramolecular electron transfer processes

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The present account summarizes our work on mononuclear vinyl ruthenium complexes of the type RuCl(CH=CH')(CO)(PR(3))(2)L, divinyl-bridged diruthenium complexes {RuCl(CO)(PR(3))(2)L}(2)(l-CH=CHbridge-CH=CH) and on heterobinuclear systems where only one of the two redox-active metal-organic moieties is of the vinyl ruthenium type. The favourable electrochemical properties of the {RuCl( CO)(PR(3))(2)L(CH=CH-) tag and the various spectroscopic handles offered by that unit provide detailed insights into the charge and spin delocalization over the {MCl(CO)(PR(3))(2)L} and CH=CHR' constituents in their associated radical cations. They also offer a convenient means for measuring electronic coupling in the mixed-valent radical cations of the homo-and heterodinuclear vinyl-bridged complexes and, under favourable circumstances, on the rate of intramolecular electron transfer between the individual redox sites. The present account summarizes our work on mononuclear vinyl ruthenium complexes of the type RuCl(CH=CH')(CO)(PR(3))(2)L, divinyl-bridged diruthenium complexes {RuCl(CO)(PR(3))(2)L}(2)(l-CH=CHbridge-CH=CH) and on heterobinuclear systems where only one of the two redox-active metal-organic moieties is of the vinyl ruthenium type. The favourable electrochemical properties of the {RuCl( CO)(PR(3))(2)L(CH=CH-) tag and the various spectroscopic handles offered by that unit provide detailed insights into the charge and spin delocalization over the {MCl(CO)(PR(3))(2)L} and CH=CHR' constituents in their associated radical cations. They also offer a convenient means for measuring electronic coupling in the mixed-valent radical cations of the homo-and heterodinuclear vinyl-bridged complexes and, under favourable circumstances, on the rate of intramolecular electron transfer between the individual redox sites. (en)
Title	Vinyl-ruthenium entities as markers for intramolecular electron transfer processes Vinyl-ruthenium entities as markers for intramolecular electron transfer processes (en)
skos:prefLabel	Vinyl-ruthenium entities as markers for intramolecular electron transfer processes Vinyl-ruthenium entities as markers for intramolecular electron transfer processes (en)
skos:notation	RIV/61388955:_____/11:00361465!RIV12-AV0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(KAN100400702), P(LD11086), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Záliš, Stanislav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	238463
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/11:00361465
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ruthenium; vinyl complexes; electrochemistry (en)
http://linked.open.../riv/klicoveSlovo	vinyl complexes electrochemistry ruthenium
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[2B921D9D7F57]
http://linked.open...i/riv/nazevZdroje	Inorganica chimica acta
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Quantum chemical interpretation and prediction of spectral characteristics of heavy transition metal complexes Nanostructured materials for catalytic, electrocatalytic and sorption applications
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	374
http://linked.open...iv/tvurceVysledku	Záliš, Stanislav Mücke, P. Winter, R. F. Linseis, M.
http://linked.open...ain/vavai/riv/wos	000292962900006
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	0020-1693
number of pages	16 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.ica.2011.03.071

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