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rdf:type
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Description
| - An extended viologen dication 1, containing one viologen subunit, was used as a model for the inclusion complex formation between cyclodextrin (CD) molecules and molecular wires comprising several subunits. UV–Vis and fluorescence spectroscopic measurements confirmed the formation of two types of the inclusion complexes 1:1 and 2:1 between αCD and 1 in the aqueous solution containing 20% of ethanol. The complex formation constants were obtained from the fluorescence spectral changes: K a = 25 3 mM1 for [αCD–1] complex and K a = 0.21 0.07 mM2 for [(αCD)2–1] complex, respectively. Cyclodextrins βCD and γCD do not form the inclusion complexes with 1 in these aqueous solutions. The time-dependent differential capacitance measurements confirmed the adsorption of 1 in the form of a complex at the electrode/electrolyte interface.
- An extended viologen dication 1, containing one viologen subunit, was used as a model for the inclusion complex formation between cyclodextrin (CD) molecules and molecular wires comprising several subunits. UV–Vis and fluorescence spectroscopic measurements confirmed the formation of two types of the inclusion complexes 1:1 and 2:1 between αCD and 1 in the aqueous solution containing 20% of ethanol. The complex formation constants were obtained from the fluorescence spectral changes: K a = 25 3 mM1 for [αCD–1] complex and K a = 0.21 0.07 mM2 for [(αCD)2–1] complex, respectively. Cyclodextrins βCD and γCD do not form the inclusion complexes with 1 in these aqueous solutions. The time-dependent differential capacitance measurements confirmed the adsorption of 1 in the form of a complex at the electrode/electrolyte interface. (en)
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Title
| - Inclusion complex of α-cyclodextrin and the extended viologen dication: a model of an insulated molecular wire
- Inclusion complex of α-cyclodextrin and the extended viologen dication: a model of an insulated molecular wire (en)
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skos:prefLabel
| - Inclusion complex of α-cyclodextrin and the extended viologen dication: a model of an insulated molecular wire
- Inclusion complex of α-cyclodextrin and the extended viologen dication: a model of an insulated molecular wire (en)
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skos:notation
| - RIV/61388955:_____/11:00361419!RIV12-GA0-61388955
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/08/1157), P(GA203/09/1607), P(IAA400400802), P(LC510), P(MEB041006), P(OC 140), Z(AV0Z40400503), Z(AV0Z40550506)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/11:00361419
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - alpha-cyclodextrin; extended viologen; complex formation (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Inclusion Phenomena and Macrocyclic Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Gál, Miroslav
- Hromadová, Magdaléna
- Kolivoška, Viliam
- Pospíšil, Lubomír
- Sokolová, Romana
- Valášek, Michal
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1007/s10847-010-9897-y
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