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  • The article reports on our continued investigation of modification of the gold electrode surface by thiolated compounds aimed at construction of an ion-selective sensor. Our previous work was focused on utilization of calix[4]arene molecules as a cavity sized ligand molecule. In this paper, calixarene and linear undecanethiol molecules were used as modifiers. We compared two ways of deposition thiol molecules, namely the spontaneous self-assembly process and the electrochemical deposition, in which the potential was applied on the electrode immersed into an adsorption solution. The concentration, time and potential conditions were optimized from the point of view of the SAM homogeneity. The modifying layers of calixarene and undecanthiol molecules were visualized by atomic force microscopy.
  • The article reports on our continued investigation of modification of the gold electrode surface by thiolated compounds aimed at construction of an ion-selective sensor. Our previous work was focused on utilization of calix[4]arene molecules as a cavity sized ligand molecule. In this paper, calixarene and linear undecanethiol molecules were used as modifiers. We compared two ways of deposition thiol molecules, namely the spontaneous self-assembly process and the electrochemical deposition, in which the potential was applied on the electrode immersed into an adsorption solution. The concentration, time and potential conditions were optimized from the point of view of the SAM homogeneity. The modifying layers of calixarene and undecanthiol molecules were visualized by atomic force microscopy. (en)
Title
  • Polycrystalline gold electrode modified by thiols
  • Polycrystalline gold electrode modified by thiols (en)
skos:prefLabel
  • Polycrystalline gold electrode modified by thiols
  • Polycrystalline gold electrode modified by thiols (en)
skos:notation
  • RIV/61388955:_____/11:00359939!RIV12-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(IAA400400806), P(LC06063), Z(AV0Z40400503)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
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  • 221199
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/11:00359939
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • undecanethiol; electrodeposition; cyclic voltammetry (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [35E20494B3CC]
http://linked.open...v/mistoKonaniAkce
  • Jetřichovice
http://linked.open...i/riv/mistoVydani
  • Ústí nad Labem
http://linked.open...i/riv/nazevZdroje
  • Sborník přednášek. XXXI. Moderní elektrochemické metody
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Mareček, Vladimír
  • Štulík, K.
  • Šustrová, Barbora
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • BEST servis
https://schema.org/isbn
  • 978-80-254-9634-3
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